Syntheses and crystal structures of the cerium-based coordination polymers poly[(acetic acid)bis(μ-5-carboxythiophene-2-carboxylato)bis(μ-thiophene-2,5-dicarboxylato)dicerium(III)] and poly[(μ-acetato)aqua(μ4-thiophene-2,5-dicarboxylato)cerium(III)]
The title compounds, [Ce2(C6H3SO4)2(C6H2SO4)2(CH3COOH)]n (1) and [Ce(CH3COO)(C6H2SO4)(H2O)]n (2) were synthesized by solvothermal reaction of Ce(NO3)3·6H2O with 2,5-thiophenedicarboxylic acid (H2TDC, C6H4SO4) and acetic acid in acetonitrile or ethanol/water, respectively. These compounds were obtain...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2025-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2056989025000210 |
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