l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides
Abstract Palladium nanoparticles were supported on L-H-functionalized KIT-6 (KIT-6@L-H-Pd) and evaluated using various characterization techniques such as TGA, FT-IR, SEM, XRD, EDS, and BET. KIT-6@L-H-Pd showed excellent catalytic performance as a recyclable nanocatalyst for the oxidation of sulfide...
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Nature Portfolio
2025-01-01
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| Series: | Scientific Reports |
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| Online Access: | https://doi.org/10.1038/s41598-025-86579-7 |
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| author | Nafis Ahmad Prakash Kanjariya G. Padma Priya Anjan Kumar Rishabh Thakur R. S. K. Sharma Mukesh Kumari Sharnjeet Kaur Abhinav Kumar Munther Kadheem |
| author_facet | Nafis Ahmad Prakash Kanjariya G. Padma Priya Anjan Kumar Rishabh Thakur R. S. K. Sharma Mukesh Kumari Sharnjeet Kaur Abhinav Kumar Munther Kadheem |
| author_sort | Nafis Ahmad |
| collection | DOAJ |
| description | Abstract Palladium nanoparticles were supported on L-H-functionalized KIT-6 (KIT-6@L-H-Pd) and evaluated using various characterization techniques such as TGA, FT-IR, SEM, XRD, EDS, and BET. KIT-6@L-H-Pd showed excellent catalytic performance as a recyclable nanocatalyst for the oxidation of sulfides to sulfoxides and the amination of aryl halides. This approach offers multiple benefits, including the use of readily available and cost-effective materials, a straightforward procedure, short reaction durations, high yields, and a catalyst that is easy to separate and reuse. Additionally, the catalyst can be recovered and reused multiple times without significant palladium loss or alteration in its activity. |
| format | Article |
| id | doaj-art-71019e9975ae4eda8f9b3944d12dcbdb |
| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj-art-71019e9975ae4eda8f9b3944d12dcbdb2025-01-26T12:25:56ZengNature PortfolioScientific Reports2045-23222025-01-0115111310.1038/s41598-025-86579-7l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halidesNafis Ahmad0Prakash Kanjariya1G. Padma Priya2Anjan Kumar3Rishabh Thakur4R. S. K. Sharma5Mukesh Kumari6Sharnjeet Kaur7Abhinav Kumar8Munther Kadheem9Department of Physics, College of Science, King Khalid UniversityDepartment of Physics, Faculty of Science, Marwadi University Research Center, Marwadi UniversityDepartment of Chemistry and Biochemistry, School of Sciences, JAIN (Deemed to be University)Department of Electronics and Communication Engineering, GLA UniversityCentre for Research Impact & Outcome, Chitkara University Institute of Engineering and Technology, Chitkara UniversityDepartment of Chemistry, Raghu Engineering CollegeDepartment of Applied Sciences-Chemistry, NIMS Institute of Engineering & Technology, NIMS University RajasthanDepartment of Applied Sciences, Chandigarh Engineering College, Chandigarh Group of Colleges-JhanjeriDepartment of Nuclear and Renewable Energy, Ural Federal University Named After the First President of Russia Boris YeltsinCollege of Pharmacy, The Islamic UniversityAbstract Palladium nanoparticles were supported on L-H-functionalized KIT-6 (KIT-6@L-H-Pd) and evaluated using various characterization techniques such as TGA, FT-IR, SEM, XRD, EDS, and BET. KIT-6@L-H-Pd showed excellent catalytic performance as a recyclable nanocatalyst for the oxidation of sulfides to sulfoxides and the amination of aryl halides. This approach offers multiple benefits, including the use of readily available and cost-effective materials, a straightforward procedure, short reaction durations, high yields, and a catalyst that is easy to separate and reuse. Additionally, the catalyst can be recovered and reused multiple times without significant palladium loss or alteration in its activity.https://doi.org/10.1038/s41598-025-86579-7KIT-6GreenSulfoxideNovelAmination |
| spellingShingle | Nafis Ahmad Prakash Kanjariya G. Padma Priya Anjan Kumar Rishabh Thakur R. S. K. Sharma Mukesh Kumari Sharnjeet Kaur Abhinav Kumar Munther Kadheem l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides Scientific Reports KIT-6 Green Sulfoxide Novel Amination |
| title | l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides |
| title_full | l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides |
| title_fullStr | l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides |
| title_full_unstemmed | l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides |
| title_short | l-Histidine-functionalized KIT-6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides |
| title_sort | l histidine functionalized kit 6 with embedded palladium nanoparticles as an efficient heterogeneous catalyst for oxidation of sulfide to sulfoxide and amination of aryl halides |
| topic | KIT-6 Green Sulfoxide Novel Amination |
| url | https://doi.org/10.1038/s41598-025-86579-7 |
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