High-spin surface FeIV = O synthesis with molecular oxygen and pyrite for selective methane oxidation
Abstract Nature-inspired high-spin FeIV = O generation enables efficient ambient methane oxidation. By engineering sulfur-bridged dual ≡FeII…FeII≡ sites on pyrite (FeS2) mimicking soluble methane monooxygenase, we achieve O2-driven formation of high-spin (S = 2) surface FeIV = O species at room temp...
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| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-08-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-025-63087-w |
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