Stereoelectronic Effect of Protecting Groups on the Stability of Galactosyl Donor Intermediates

Stereoelectronic Effect of Protecting Groups on the Stability of Galactosyl Donor Intermediates

Using methods of DFT, we investigated the effect of electron withdrawing and electron donating groups on the relative stability of tentative glycosyl donor reaction intermediates. The calculation shows that by changing the stereoelectronic properties of the protecting group, we can influence the sta...

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Bibliographic Details
Main Authors: Ryan W. Kwok, Ryan Rutkoski, Pavel Nagorny, Mateusz Marianski
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Molecules
Subjects:
glycosylation mechanism
DFT
remote participation
Online Access:https://www.mdpi.com/1420-3049/30/2/218
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