Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes

The runoff components were identified in the headwater area of Shule River Basin, using isotopic and chemical tracing with particular focus on the temporal variations of catchment sources. A total of 95 samples, including precipitation, groundwater, and glacial meltwater, were collected and analyze...

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Main Authors: Jiaxin Zhou, Jinkui Wu, Shiwei Liu, Guoxiong Zeng, Jia Qin, Xiuna Wang, Qiudong Zhao
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Advances in Meteorology
Online Access:http://dx.doi.org/10.1155/2015/830306
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author Jiaxin Zhou
Jinkui Wu
Shiwei Liu
Guoxiong Zeng
Jia Qin
Xiuna Wang
Qiudong Zhao
author_facet Jiaxin Zhou
Jinkui Wu
Shiwei Liu
Guoxiong Zeng
Jia Qin
Xiuna Wang
Qiudong Zhao
author_sort Jiaxin Zhou
collection DOAJ
description The runoff components were identified in the headwater area of Shule River Basin, using isotopic and chemical tracing with particular focus on the temporal variations of catchment sources. A total of 95 samples, including precipitation, groundwater, and glacial meltwater, were collected and analyzed for stable water isotopes (18O and 2H) and major chemical ion parameters (potassium, sodium, calcium, magnesium, sulfate, chloride, and bicarbonate). Based on the isotope and water chemistry data, we applied end member mixing analysis (EMMA) to identify and quantify the major runoff generating sources and their contributions. The contributions of groundwater, precipitation, and glacial meltwater were 66.7%, 19.9%, and 13.4%, respectively. The study indicated that groundwater dominated runoff in the headwater area of Shule River Basin. The roles of glacier meltwater should be remarkable in water resource management in this basin. The uncertainties of the EMMA method were summarized and estimated via a classical Gaussian error propagation technique. Analyses suggested that the uncertainty in the measurement method was less important than that in the temporal and spatial variations of tracer concentrations. The uncertainty was sensitive when the difference between mixing components was small. Therefore, the variation of tracers and the difference of mixing components should be considered when hydrograph separation was applied in the basin.
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institution Kabale University
issn 1687-9309
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language English
publishDate 2015-01-01
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series Advances in Meteorology
spelling doaj-art-64c9375b776e49cba0f5899dfd7520b52025-02-03T00:59:22ZengWileyAdvances in Meteorology1687-93091687-93172015-01-01201510.1155/2015/830306830306Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable IsotopesJiaxin Zhou0Jinkui Wu1Shiwei Liu2Guoxiong Zeng3Jia Qin4Xiuna Wang5Qiudong Zhao6Laboratory of Watershed Hydrology and Ecology, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, ChinaLaboratory of Watershed Hydrology and Ecology, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, ChinaLaboratory of Watershed Hydrology and Ecology, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, ChinaShule River Basin Water Resources Administration of Gansu Province, Yumen 735200, ChinaLaboratory of Watershed Hydrology and Ecology, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, ChinaLaboratory of Watershed Hydrology and Ecology, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, ChinaLaboratory of Watershed Hydrology and Ecology, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, ChinaThe runoff components were identified in the headwater area of Shule River Basin, using isotopic and chemical tracing with particular focus on the temporal variations of catchment sources. A total of 95 samples, including precipitation, groundwater, and glacial meltwater, were collected and analyzed for stable water isotopes (18O and 2H) and major chemical ion parameters (potassium, sodium, calcium, magnesium, sulfate, chloride, and bicarbonate). Based on the isotope and water chemistry data, we applied end member mixing analysis (EMMA) to identify and quantify the major runoff generating sources and their contributions. The contributions of groundwater, precipitation, and glacial meltwater were 66.7%, 19.9%, and 13.4%, respectively. The study indicated that groundwater dominated runoff in the headwater area of Shule River Basin. The roles of glacier meltwater should be remarkable in water resource management in this basin. The uncertainties of the EMMA method were summarized and estimated via a classical Gaussian error propagation technique. Analyses suggested that the uncertainty in the measurement method was less important than that in the temporal and spatial variations of tracer concentrations. The uncertainty was sensitive when the difference between mixing components was small. Therefore, the variation of tracers and the difference of mixing components should be considered when hydrograph separation was applied in the basin.http://dx.doi.org/10.1155/2015/830306
spellingShingle Jiaxin Zhou
Jinkui Wu
Shiwei Liu
Guoxiong Zeng
Jia Qin
Xiuna Wang
Qiudong Zhao
Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes
Advances in Meteorology
title Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes
title_full Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes
title_fullStr Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes
title_full_unstemmed Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes
title_short Hydrograph Separation in the Headwaters of the Shule River Basin: Combining Water Chemistry and Stable Isotopes
title_sort hydrograph separation in the headwaters of the shule river basin combining water chemistry and stable isotopes
url http://dx.doi.org/10.1155/2015/830306
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