Dissipation and Residues of Thiram in Potato and Soil

The residue levels of thiram during potato cultivation in open field were evaluated. Thiram residues were determined by methylation derivation method with high performance liquid chromatography (HPLC). Wettable powder (WP) formulation containing 25% thiram was applied at 2320 g active gradient hm−2...

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Main Authors: Shaowen Liu, Aijuan Bai, Li Zhou, Chuanshan Yu, Yanjie Li, Sufang Fan, Canping Pan
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2015/623847
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author Shaowen Liu
Aijuan Bai
Li Zhou
Chuanshan Yu
Yanjie Li
Sufang Fan
Canping Pan
author_facet Shaowen Liu
Aijuan Bai
Li Zhou
Chuanshan Yu
Yanjie Li
Sufang Fan
Canping Pan
author_sort Shaowen Liu
collection DOAJ
description The residue levels of thiram during potato cultivation in open field were evaluated. Thiram residues were determined by methylation derivation method with high performance liquid chromatography (HPLC). Wettable powder (WP) formulation containing 25% thiram was applied at 2320 g active gradient hm−2 (a.i. hm−2) dosage for the dissipation study. The decline rate in potato leave and soil followed first-order kinetics equation, and the half-life ranged from 2.8 to 5.4 days and 2.6 to 9.9 days, respectively. In terminal residue, the thiram was sprayed at 580 g a.i. hm−2 (low concentration, recommended dosage) and 1160 g a.i. hm−2 (high concentration, double of recommended dosage). The residues of thiram in potato and soil samples collected in the field at preharvest interval of 21 days and 30 days were all below 0.02 mg kg−1. The results show that thiram possesses low dietary risk in potato at harvest according to supervised residue field trial. It may be safe when used at recommended rate of application.
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institution Kabale University
issn 2090-9063
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language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-6016e2095a9148e3966746adbdf7b68d2025-02-03T01:06:56ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/623847623847Dissipation and Residues of Thiram in Potato and SoilShaowen Liu0Aijuan Bai1Li Zhou2Chuanshan Yu3Yanjie Li4Sufang Fan5Canping Pan6Department of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaDepartment of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaDepartment of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaDepartment of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaDepartment of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaDepartment of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaDepartment of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, ChinaThe residue levels of thiram during potato cultivation in open field were evaluated. Thiram residues were determined by methylation derivation method with high performance liquid chromatography (HPLC). Wettable powder (WP) formulation containing 25% thiram was applied at 2320 g active gradient hm−2 (a.i. hm−2) dosage for the dissipation study. The decline rate in potato leave and soil followed first-order kinetics equation, and the half-life ranged from 2.8 to 5.4 days and 2.6 to 9.9 days, respectively. In terminal residue, the thiram was sprayed at 580 g a.i. hm−2 (low concentration, recommended dosage) and 1160 g a.i. hm−2 (high concentration, double of recommended dosage). The residues of thiram in potato and soil samples collected in the field at preharvest interval of 21 days and 30 days were all below 0.02 mg kg−1. The results show that thiram possesses low dietary risk in potato at harvest according to supervised residue field trial. It may be safe when used at recommended rate of application.http://dx.doi.org/10.1155/2015/623847
spellingShingle Shaowen Liu
Aijuan Bai
Li Zhou
Chuanshan Yu
Yanjie Li
Sufang Fan
Canping Pan
Dissipation and Residues of Thiram in Potato and Soil
Journal of Chemistry
title Dissipation and Residues of Thiram in Potato and Soil
title_full Dissipation and Residues of Thiram in Potato and Soil
title_fullStr Dissipation and Residues of Thiram in Potato and Soil
title_full_unstemmed Dissipation and Residues of Thiram in Potato and Soil
title_short Dissipation and Residues of Thiram in Potato and Soil
title_sort dissipation and residues of thiram in potato and soil
url http://dx.doi.org/10.1155/2015/623847
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AT yanjieli dissipationandresiduesofthiraminpotatoandsoil
AT sufangfan dissipationandresiduesofthiraminpotatoandsoil
AT canpingpan dissipationandresiduesofthiraminpotatoandsoil