(Ph3P)4C4P4: Effect of substitution on the Oligomerization of carbon phosphide radicals

Abstract Dehalogenation of (PBr)2C2(PPh3)2 with potassium graphite, KC8, leads to Cs‐P4C4(PPh3)4, which can be viewed as a PPh3 adduct of a Cs‐symmetric P4C4 cage. An isolable intermediate was found and in combination with DFT calculations, the structure of a S4‐symmetric P4C4(PPh3)4 cage is propose...

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Bibliographic Details
Main Authors: Dr. Moritz Scharnhölz, Dr. Jose Juan Gamboa Carballo, Dr. Nils Trapp, Dr. Rene Verel, Dr. Peter Coburger, Prof. Dr. Hansjörg Grützmacher
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:ChemistryEurope
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Online Access:https://doi.org/10.1002/ceur.202400061
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