Enantioselective Assembly of Fully Substituted α‐Amino Allenoates Through a Mannich Addition and Stepwise [3,3]‐σ Rearrangement Sequence

Enantioselective Assembly of Fully Substituted α‐Amino Allenoates Through a Mannich Addition and Stepwise [3,3]‐σ Rearrangement Sequence

Abstract Chiral fully‐substituted allenes are synthetically significant and pivotal building blocks that can engage in diverse transformations toward a variety of bioactive molecules. The enantioselective assembly of these skeletons using readily available reactants offers significant advantages but...

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Bibliographic Details
Main Authors: Haoxuan Yuan, Yi Zhou, Xiongda Xie, Ming Bao, Kewei Chen, Kemiao Hong, Zhixiang Yu, Xinfang Xu
Format: Article
Language:English
Published: Wiley 2025-01-01
Series:Advanced Science
Subjects:
alkyne functionalization
asymmetric catalysis
cooperative catalysis
gold catalysis
α‐amino allenoate
Online Access:https://doi.org/10.1002/advs.202409334
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https://doi.org/10.1002/advs.202409334

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