Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix

To improve the interfacial bond properties of the carbon fiber coated with a nano-SiO2 particle in a cement paste matrix, the present study proposed a method of coating nano-SiO2 particles on the surface of the carbon fiber by the chemical reaction of a silane coupling agent (glycidoxypropyltrimetho...

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Main Authors: Gwang-Hee Heo, Jong-Gun Park, Ki-Chang Song, Jong-Ho Park, Hyung-Min Jun
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2020/8838179
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author Gwang-Hee Heo
Jong-Gun Park
Ki-Chang Song
Jong-Ho Park
Hyung-Min Jun
author_facet Gwang-Hee Heo
Jong-Gun Park
Ki-Chang Song
Jong-Ho Park
Hyung-Min Jun
author_sort Gwang-Hee Heo
collection DOAJ
description To improve the interfacial bond properties of the carbon fiber coated with a nano-SiO2 particle in a cement paste matrix, the present study proposed a method of coating nano-SiO2 particles on the surface of the carbon fiber by the chemical reaction of a silane coupling agent (glycidoxypropyltrimethoxysilane, GPTMS) and colloidal nano-SiO2 sol in an alkaline environment. To verify whether a nano-SiO2 particle was effectively modified on the surface of the carbon fiber, the surface morphology, chemical composition, and chemical structure were characterized and analyzed by several techniques such as the scanning electron microscope (SEM), energy-dispersive spectrometer (EDS), and Fourier-transform infrared spectroscopy (FT-IR). Nano-SiO2 particles were entirely covered and uniformly distributed on the surface of the carbon fiber, resulting in the formation of a thin layer of nano-SiO2 particles. A thin layer of nano-SiO2 particles reacted with Ca(OH)2 to form a calcium-silicate-hydrate (C-S-H) gel, which is most helpful to increase the form between the fiber and the matrix. In addition, a pull-out test of the tow carbon fibers was performed to verify the effect of the new surface modification method on the interfacial bond properties of the carbon fiber embedded in the cement paste matrix. The experimental results showed that the frictional bond strength of the carbon fiber coated with a nano-SiO2 particle was significantly increased compared to the plain carbon fiber. These results were expected to improve the interfacial bonding force of hardened cement paste from the formation of the C-S-H gel produced through the chemical reaction of nano-SiO2 particles coated on the surface of the carbon fiber with Ca(OH)2. In particular, it was confirmed that the carbon fiber-reinforced cement paste (CFRCP) specimens coated with a nano-SiO2 particle and silica fume which replaced 10 wt.% of cement by mass showed the highest pull-out resistance performance at 28 days of age. The new surface modification method developed in this study can be very beneficial and helpful in improving the interfacial bond properties of CFRCP.
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spelling doaj-art-4d9e298d308a4f05a47e8d06432d39852025-02-03T01:28:33ZengWileyAdvances in Civil Engineering1687-80861687-80942020-01-01202010.1155/2020/88381798838179Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste MatrixGwang-Hee Heo0Jong-Gun Park1Ki-Chang Song2Jong-Ho Park3Hyung-Min Jun4Department of International Civil and Plant Engineering, Konyang University, 121 Daehak-Ro, Nonsan-Si, Chungnam-Do, Republic of KoreaPublic Safety Research Center (PSRC), Konyang University, 121 Dachak-Ro, Nonsan-Si, Chungnki-Changam-Do, Republic of KoreaDepartment of Biomedical Materials, Konyang University, 158 Gwanjedong-Ro, Seo-Gu, Daejeon Metropolitan-Si, Republic of KoreaDepartment of Biomedical Materials, Konyang University, 158 Gwanjedong-Ro, Seo-Gu, Daejeon Metropolitan-Si, Republic of KoreaDepartment of Disaster and Safety Engineering, Konyang University, 121 Dachak-Ro, Nonsan- Si, Chungnam-Do, Republic of KoreaTo improve the interfacial bond properties of the carbon fiber coated with a nano-SiO2 particle in a cement paste matrix, the present study proposed a method of coating nano-SiO2 particles on the surface of the carbon fiber by the chemical reaction of a silane coupling agent (glycidoxypropyltrimethoxysilane, GPTMS) and colloidal nano-SiO2 sol in an alkaline environment. To verify whether a nano-SiO2 particle was effectively modified on the surface of the carbon fiber, the surface morphology, chemical composition, and chemical structure were characterized and analyzed by several techniques such as the scanning electron microscope (SEM), energy-dispersive spectrometer (EDS), and Fourier-transform infrared spectroscopy (FT-IR). Nano-SiO2 particles were entirely covered and uniformly distributed on the surface of the carbon fiber, resulting in the formation of a thin layer of nano-SiO2 particles. A thin layer of nano-SiO2 particles reacted with Ca(OH)2 to form a calcium-silicate-hydrate (C-S-H) gel, which is most helpful to increase the form between the fiber and the matrix. In addition, a pull-out test of the tow carbon fibers was performed to verify the effect of the new surface modification method on the interfacial bond properties of the carbon fiber embedded in the cement paste matrix. The experimental results showed that the frictional bond strength of the carbon fiber coated with a nano-SiO2 particle was significantly increased compared to the plain carbon fiber. These results were expected to improve the interfacial bonding force of hardened cement paste from the formation of the C-S-H gel produced through the chemical reaction of nano-SiO2 particles coated on the surface of the carbon fiber with Ca(OH)2. In particular, it was confirmed that the carbon fiber-reinforced cement paste (CFRCP) specimens coated with a nano-SiO2 particle and silica fume which replaced 10 wt.% of cement by mass showed the highest pull-out resistance performance at 28 days of age. The new surface modification method developed in this study can be very beneficial and helpful in improving the interfacial bond properties of CFRCP.http://dx.doi.org/10.1155/2020/8838179
spellingShingle Gwang-Hee Heo
Jong-Gun Park
Ki-Chang Song
Jong-Ho Park
Hyung-Min Jun
Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix
Advances in Civil Engineering
title Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix
title_full Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix
title_fullStr Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix
title_full_unstemmed Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix
title_short Improving the Interfacial Bond Properties of the Carbon Fiber Coated with a Nano-SiO2 Particle in a Cement Paste Matrix
title_sort improving the interfacial bond properties of the carbon fiber coated with a nano sio2 particle in a cement paste matrix
url http://dx.doi.org/10.1155/2020/8838179
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