Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway

The safety of power batteries in the automotive industry is of paramount importance and cannot be emphasized enough. As lithium-ion battery technology continues to evolve, the energy density of these batteries increases, thereby amplifying the potential risks linked to battery failures. This study e...

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Main Authors: Liang Luo, Jianwei Chen, Aisn Gioronara Hui, Rongzhen Liu, Yao Zhou, Haitong Liang, Ziyuan Wang, Haosu Luo, Fei Fang
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Micromachines
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Online Access:https://www.mdpi.com/2072-666X/16/1/36
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author Liang Luo
Jianwei Chen
Aisn Gioronara Hui
Rongzhen Liu
Yao Zhou
Haitong Liang
Ziyuan Wang
Haosu Luo
Fei Fang
author_facet Liang Luo
Jianwei Chen
Aisn Gioronara Hui
Rongzhen Liu
Yao Zhou
Haitong Liang
Ziyuan Wang
Haosu Luo
Fei Fang
author_sort Liang Luo
collection DOAJ
description The safety of power batteries in the automotive industry is of paramount importance and cannot be emphasized enough. As lithium-ion battery technology continues to evolve, the energy density of these batteries increases, thereby amplifying the potential risks linked to battery failures. This study explores pivotal safety challenges within the electric vehicle sector, with a particular focus on thermal runaway and gas emissions originating from lithium-ion batteries. We offer a non-dispersive infrared (NDIR) gas sensor designed to efficiently monitor battery emissions. Notably, carbon dioxide (CO<sub>2</sub>) gas sensors are emphasized for their ability to enhance early-warning systems, facilitating the timely detection of potential issues and, in turn, improving the overall safety standards of electric vehicles. In this study, we introduce a novel CO<sub>2</sub> gas sensor based on the advanced pyroelectric single-crystal lead niobium magnesium titanate (PMNT), which exhibits exceptionally high pyroelectric properties compared to commercially available materials, such as lithium tantalate single crystals and lead zirconate titanate ceramics. The specific detection rate of PMNT single-crystal pyroelectric infrared detectors is more than four times higher than lithium tantalate single-crystal infrared detectors. The PMNT single-crystal NDIR gas detector is used to monitor thermal runaway in lithium-ion batteries, enabling the rapid and highly accurate detection of gases released by the battery. This research offers an in-depth exploration of real-time monitoring for power battery safety, utilizing the cutting-edge pyroelectric single-crystal gas sensor. Beyond providing valuable insights, the study also presents practical recommendations for mitigating the risks of thermal runaway in lithium-ion batteries, with a particular emphasis on the development of effective warning systems.
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publishDate 2024-12-01
publisher MDPI AG
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series Micromachines
spelling doaj-art-48d74f4ada3149b6ba07e7633c897f892025-01-24T13:41:55ZengMDPI AGMicromachines2072-666X2024-12-011613610.3390/mi16010036Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal RunawayLiang Luo0Jianwei Chen1Aisn Gioronara Hui2Rongzhen Liu3Yao Zhou4Haitong Liang5Ziyuan Wang6Haosu Luo7Fei Fang8Department of Engineering Mechanics, Tsinghua University, Beijing 100084, ChinaShanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, ChinaEinsteck Inc., Palo Alto, CA 94305, USASchool of Instrument and Electronics, North University of China, Taiyuan 030051, ChinaSchool of Modern Post, Xi’an University of Posts and Telecommunications, Xi’an 710061, ChinaCollege of Materials Science and Technology, Beijing Forestry University, Beijing 100083, ChinaSchool of Integrated Circuits, Southeast University, Nanjing 214135, ChinaShanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, ChinaDepartment of Engineering Mechanics, Tsinghua University, Beijing 100084, ChinaThe safety of power batteries in the automotive industry is of paramount importance and cannot be emphasized enough. As lithium-ion battery technology continues to evolve, the energy density of these batteries increases, thereby amplifying the potential risks linked to battery failures. This study explores pivotal safety challenges within the electric vehicle sector, with a particular focus on thermal runaway and gas emissions originating from lithium-ion batteries. We offer a non-dispersive infrared (NDIR) gas sensor designed to efficiently monitor battery emissions. Notably, carbon dioxide (CO<sub>2</sub>) gas sensors are emphasized for their ability to enhance early-warning systems, facilitating the timely detection of potential issues and, in turn, improving the overall safety standards of electric vehicles. In this study, we introduce a novel CO<sub>2</sub> gas sensor based on the advanced pyroelectric single-crystal lead niobium magnesium titanate (PMNT), which exhibits exceptionally high pyroelectric properties compared to commercially available materials, such as lithium tantalate single crystals and lead zirconate titanate ceramics. The specific detection rate of PMNT single-crystal pyroelectric infrared detectors is more than four times higher than lithium tantalate single-crystal infrared detectors. The PMNT single-crystal NDIR gas detector is used to monitor thermal runaway in lithium-ion batteries, enabling the rapid and highly accurate detection of gases released by the battery. This research offers an in-depth exploration of real-time monitoring for power battery safety, utilizing the cutting-edge pyroelectric single-crystal gas sensor. Beyond providing valuable insights, the study also presents practical recommendations for mitigating the risks of thermal runaway in lithium-ion batteries, with a particular emphasis on the development of effective warning systems.https://www.mdpi.com/2072-666X/16/1/36non-dispersive infraredpyroelectriccarbon dioxide gas sensorlead niobium magnesium titanate
spellingShingle Liang Luo
Jianwei Chen
Aisn Gioronara Hui
Rongzhen Liu
Yao Zhou
Haitong Liang
Ziyuan Wang
Haosu Luo
Fei Fang
Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway
Micromachines
non-dispersive infrared
pyroelectric
carbon dioxide gas sensor
lead niobium magnesium titanate
title Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway
title_full Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway
title_fullStr Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway
title_full_unstemmed Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway
title_short Highly Sensitive Non-Dispersive Infrared Gas Sensor with Innovative Application for Monitoring Carbon Dioxide Emissions from Lithium-Ion Battery Thermal Runaway
title_sort highly sensitive non dispersive infrared gas sensor with innovative application for monitoring carbon dioxide emissions from lithium ion battery thermal runaway
topic non-dispersive infrared
pyroelectric
carbon dioxide gas sensor
lead niobium magnesium titanate
url https://www.mdpi.com/2072-666X/16/1/36
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