Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions
The values of pseudo-first-order rate constants (kobs) for alkaline hydrolysis of 1, obtained at 1.0 mM NaOH and within CmEnT (total concentration of CmEn) range of 3.0–5.0 mM for C12E23 and 10–20 mM for C18E20, fail to obey pseudophase micellar (PM) model. The values of the fraction of near irrever...
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Wiley
2014-01-01
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| Series: | The Scientific World Journal |
| Online Access: | http://dx.doi.org/10.1155/2014/592691 |
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| author | M. Niyaz Khan Yoke-Leng Sim Azhar Ariffin |
| author_facet | M. Niyaz Khan Yoke-Leng Sim Azhar Ariffin |
| author_sort | M. Niyaz Khan |
| collection | DOAJ |
| description | The values of pseudo-first-order rate constants (kobs) for alkaline hydrolysis of 1, obtained at 1.0 mM NaOH and within CmEnT (total concentration of CmEn) range of 3.0–5.0 mM for C12E23 and 10–20 mM for C18E20, fail to obey pseudophase micellar (PM) model. The values of the fraction of near irreversible CmEn micellar trapped 1 molecules (FIT1) vary in the range ~0–0.75 for C12E23 and ~0–0.83 for C18E20 under such conditions. The values of FIT1 become 1.0 at ≥10 mM C12E23 and 50 mM C18E20. Kinetic analysis of the observed data at ≥10 mM C12E23 shows near irreversible micellar entrapment of 1 molecules under such conditions. |
| format | Article |
| id | doaj-art-3ec2d6c25a16491080082acf8621a8b3 |
| institution | Kabale University |
| issn | 2356-6140 1537-744X |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | The Scientific World Journal |
| spelling | doaj-art-3ec2d6c25a16491080082acf8621a8b32025-02-03T00:59:14ZengWileyThe Scientific World Journal2356-61401537-744X2014-01-01201410.1155/2014/592691592691Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction ConditionsM. Niyaz Khan0Yoke-Leng Sim1Azhar Ariffin2Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MalaysiaDepartment of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MalaysiaDepartment of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MalaysiaThe values of pseudo-first-order rate constants (kobs) for alkaline hydrolysis of 1, obtained at 1.0 mM NaOH and within CmEnT (total concentration of CmEn) range of 3.0–5.0 mM for C12E23 and 10–20 mM for C18E20, fail to obey pseudophase micellar (PM) model. The values of the fraction of near irreversible CmEn micellar trapped 1 molecules (FIT1) vary in the range ~0–0.75 for C12E23 and ~0–0.83 for C18E20 under such conditions. The values of FIT1 become 1.0 at ≥10 mM C12E23 and 50 mM C18E20. Kinetic analysis of the observed data at ≥10 mM C12E23 shows near irreversible micellar entrapment of 1 molecules under such conditions.http://dx.doi.org/10.1155/2014/592691 |
| spellingShingle | M. Niyaz Khan Yoke-Leng Sim Azhar Ariffin Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions The Scientific World Journal |
| title | Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions |
| title_full | Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions |
| title_fullStr | Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions |
| title_full_unstemmed | Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions |
| title_short | Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions |
| title_sort | kinetic evidence for near irreversible nonionic micellar entrapment of n 2 methoxyphenyl phthalimide 1 under the typical alkaline reaction conditions |
| url | http://dx.doi.org/10.1155/2014/592691 |
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