Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media

Recently, iron nanoparticles have attracted more attention for groundwater remediation due to its potential to reduce subsurface contaminants such as PCBs, chlorinated solvents, and heavy metals. The magnetic properties of iron nanoparticles cause to attach to each other and form bigger colloid part...

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Main Authors: M. Golzar, S. F. Saghravani, M. Azhdari Moghaddam
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2014/864068
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author M. Golzar
S. F. Saghravani
M. Azhdari Moghaddam
author_facet M. Golzar
S. F. Saghravani
M. Azhdari Moghaddam
author_sort M. Golzar
collection DOAJ
description Recently, iron nanoparticles have attracted more attention for groundwater remediation due to its potential to reduce subsurface contaminants such as PCBs, chlorinated solvents, and heavy metals. The magnetic properties of iron nanoparticles cause to attach to each other and form bigger colloid particles of iron nanoparticles with more rapid sedimentation rate in aqueous environment. Using the surfactants such as poly acrylic acid (PAA) prevents iron nanoparticles from forming large flocs that may cause sedimentation and so increases transport distance of the nanoparticles. In this study, the transport of iron oxide nanoparticles (Fe3O4) stabilized with PAA in a one-dimensional porous media (column) was investigated. The slurries with concentrations of 20,100 and 500 (mg/L) were injected into the bottom of the column under hydraulic gradients of 0.125, 0.375, and 0.625. The results obtained from experiments were compared with the results obtained from numerical solution of advection-dispersion equation based on the classical colloid filtration theory (CFT). The experimental and simulated breakthrough curves showed that CFT is able to predict the transport and fate of iron oxide nanoparticles stabilized with PAA (up to concentration 500 ppm) in a porous media.
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spelling doaj-art-3b6afbcaae6145d8a606efc83ebac24a2025-02-03T05:57:47ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422014-01-01201410.1155/2014/864068864068Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous MediaM. Golzar0S. F. Saghravani1M. Azhdari Moghaddam2Department of Civil Engineering, University of Shahrood, Shahrood 3619995161, IranDepartment of Civil Engineering, University of Shahrood, Shahrood 3619995161, IranDepartment of Civil Engineering, University of Sistan and Baluchestan, Zahedan, IranRecently, iron nanoparticles have attracted more attention for groundwater remediation due to its potential to reduce subsurface contaminants such as PCBs, chlorinated solvents, and heavy metals. The magnetic properties of iron nanoparticles cause to attach to each other and form bigger colloid particles of iron nanoparticles with more rapid sedimentation rate in aqueous environment. Using the surfactants such as poly acrylic acid (PAA) prevents iron nanoparticles from forming large flocs that may cause sedimentation and so increases transport distance of the nanoparticles. In this study, the transport of iron oxide nanoparticles (Fe3O4) stabilized with PAA in a one-dimensional porous media (column) was investigated. The slurries with concentrations of 20,100 and 500 (mg/L) were injected into the bottom of the column under hydraulic gradients of 0.125, 0.375, and 0.625. The results obtained from experiments were compared with the results obtained from numerical solution of advection-dispersion equation based on the classical colloid filtration theory (CFT). The experimental and simulated breakthrough curves showed that CFT is able to predict the transport and fate of iron oxide nanoparticles stabilized with PAA (up to concentration 500 ppm) in a porous media.http://dx.doi.org/10.1155/2014/864068
spellingShingle M. Golzar
S. F. Saghravani
M. Azhdari Moghaddam
Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media
Advances in Materials Science and Engineering
title Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media
title_full Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media
title_fullStr Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media
title_full_unstemmed Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media
title_short Experimental Study and Numerical Solution of Poly Acrylic Acid Supported Magnetite Nanoparticles Transport in a One-Dimensional Porous Media
title_sort experimental study and numerical solution of poly acrylic acid supported magnetite nanoparticles transport in a one dimensional porous media
url http://dx.doi.org/10.1155/2014/864068
work_keys_str_mv AT mgolzar experimentalstudyandnumericalsolutionofpolyacrylicacidsupportedmagnetitenanoparticlestransportinaonedimensionalporousmedia
AT sfsaghravani experimentalstudyandnumericalsolutionofpolyacrylicacidsupportedmagnetitenanoparticlestransportinaonedimensionalporousmedia
AT mazhdarimoghaddam experimentalstudyandnumericalsolutionofpolyacrylicacidsupportedmagnetitenanoparticlestransportinaonedimensionalporousmedia