Cluster-spin-glass behavior in new ternary RE2PtGe3 compounds (RE = Tb, Dy, Ho)

Two new ternary germanides Tb _2 Pt _1.2 Ge _2.8 , Dy _2 Pt _1.15 Ge _2.85 and one already known germanium Ho _2 Pt _1.1 Ge _2.9. were synthesized using an arc melting technique. The obtained samples were investigated by powder x-ray diffraction, which indicated that all of them crystallized in a he...

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Main Authors: L S Litzbarski, M J Winiarski, I Oshchapovsky, P Skokowski, K Synoradzki, T Klimczuk, B Andrzejewski
Format: Article
Language:English
Published: IOP Publishing 2024-01-01
Series:Materials Research Express
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Online Access:https://doi.org/10.1088/2053-1591/ad7444
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Summary:Two new ternary germanides Tb _2 Pt _1.2 Ge _2.8 , Dy _2 Pt _1.15 Ge _2.85 and one already known germanium Ho _2 Pt _1.1 Ge _2.9. were synthesized using an arc melting technique. The obtained samples were investigated by powder x-ray diffraction, which indicated that all of them crystallized in a hexagonal structure with P 6/ mmm (no. 191) space group. This structure is a disordered variant of the AlB _2 aristotype that favors the formation of a spin-glass-like state. The physical properties were examined by measuring magnetic susceptibility, heat capacity and electrical resistance. Experiments indicated that all of the compounds can be classified as cluster-spin-glasses with the freezing temperature of T _f = 12.0 K, T _f = 6.0 K and T _f = 2.9 K for Tb _2 Pt _1.2 Ge _2.8 , Dy _2 Pt _1.15 Ge _2.85 and Ho _2 Pt _1.1 Ge _2.9 respectively.
ISSN:2053-1591