Rh(III)-Catalyzed Double Annulation of 3-Phenyl-1,2,4-oxadiazoles with 2-Diazo-1,3-diketones: Access to Pyran-Fused Isoquinolines

Rh(III)-Catalyzed Double Annulation of 3-Phenyl-1,2,4-oxadiazoles with 2-Diazo-1,3-diketones: Access to Pyran-Fused Isoquinolines

Efficient access to pyranoisoquinoline derivatives via rhodium-catalyzed double C-H functionalization of phenyl oxadiazoles and diazo compounds has been developed. Two C-C bonds and one C-O and C-N bond formation was realized by this tandem reaction, along with the formation of two heterocycles, aff...

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Bibliographic Details
Main Authors: Enshen Zhang, Mei Sun, Lvlv Gao
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Molecules
Subjects:
annulations
C-H bond activation
diazo compounds
oxadiazole
pyranoisoquinolines
Online Access:https://www.mdpi.com/1420-3049/30/1/149
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