Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands
Oxocyanotungsten(IV) complexes, (Ph3P)2 NH2 [WO(CN)3 L–L]. 3H2O and Cs[WO(CN)3L–L].H2O (where L–L = morpholinobenzyl benzamide (MBB), piperidinobenzyl benzamide (PBB), piperidinobenzyl urea (PBU), piperidinobenzyl thiourea (PBTU), morpholinobenzyl urea (MBU) and morpholinobenzyl thiourea (MBTU)) wer...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2010-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/378561 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832558509619675136 |
|---|---|
| author | Mohita Sharma Mohd Saleem Balgar Singh H. N. Sheikh B. L. Kalsotra |
| author_facet | Mohita Sharma Mohd Saleem Balgar Singh H. N. Sheikh B. L. Kalsotra |
| author_sort | Mohita Sharma |
| collection | DOAJ |
| description | Oxocyanotungsten(IV) complexes, (Ph3P)2 NH2 [WO(CN)3 L–L]. 3H2O and Cs[WO(CN)3L–L].H2O (where L–L = morpholinobenzyl benzamide (MBB), piperidinobenzyl benzamide (PBB), piperidinobenzyl urea (PBU), piperidinobenzyl thiourea (PBTU), morpholinobenzyl urea (MBU) and morpholinobenzyl thiourea (MBTU)) were synthesized. The complexes have been prepared by the reaction of K3Na [WO2(CN)4].6H2O with morpholinobenzyl urea and related ligands in aqueous solution around pH of 7-8. These have been isolated as bis(triphenylphosphine)iminium or cesium salts. The complexes have been characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra, magnetic susceptibility, conductivity measurements and TGA/DTA studies. |
| format | Article |
| id | doaj-art-3023f6409aaf4bf18d68e44ccb355cb7 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-3023f6409aaf4bf18d68e44ccb355cb72025-02-03T01:32:14ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-017S1S231S23810.1155/2010/378561Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base LigandsMohita Sharma0Mohd Saleem1Balgar Singh2H. N. Sheikh3B. L. Kalsotra4Department of Chemistry, University of Jammu, Jammu-180006, IndiaDepartment of Chemistry, University of Jammu, Jammu-180006, IndiaDepartment of Chemistry, University of Jammu, Jammu-180006, IndiaDepartment of Chemistry, University of Jammu, Jammu-180006, IndiaDepartment of Chemistry, University of Jammu, Jammu-180006, IndiaOxocyanotungsten(IV) complexes, (Ph3P)2 NH2 [WO(CN)3 L–L]. 3H2O and Cs[WO(CN)3L–L].H2O (where L–L = morpholinobenzyl benzamide (MBB), piperidinobenzyl benzamide (PBB), piperidinobenzyl urea (PBU), piperidinobenzyl thiourea (PBTU), morpholinobenzyl urea (MBU) and morpholinobenzyl thiourea (MBTU)) were synthesized. The complexes have been prepared by the reaction of K3Na [WO2(CN)4].6H2O with morpholinobenzyl urea and related ligands in aqueous solution around pH of 7-8. These have been isolated as bis(triphenylphosphine)iminium or cesium salts. The complexes have been characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra, magnetic susceptibility, conductivity measurements and TGA/DTA studies.http://dx.doi.org/10.1155/2010/378561 |
| spellingShingle | Mohita Sharma Mohd Saleem Balgar Singh H. N. Sheikh B. L. Kalsotra Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands E-Journal of Chemistry |
| title | Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands |
| title_full | Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands |
| title_fullStr | Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands |
| title_full_unstemmed | Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands |
| title_short | Preparation and Characterization of Cyano Complexes of Oxotungsten(IV) with Mannich Base Ligands |
| title_sort | preparation and characterization of cyano complexes of oxotungsten iv with mannich base ligands |
| url | http://dx.doi.org/10.1155/2010/378561 |
| work_keys_str_mv | AT mohitasharma preparationandcharacterizationofcyanocomplexesofoxotungstenivwithmannichbaseligands AT mohdsaleem preparationandcharacterizationofcyanocomplexesofoxotungstenivwithmannichbaseligands AT balgarsingh preparationandcharacterizationofcyanocomplexesofoxotungstenivwithmannichbaseligands AT hnsheikh preparationandcharacterizationofcyanocomplexesofoxotungstenivwithmannichbaseligands AT blkalsotra preparationandcharacterizationofcyanocomplexesofoxotungstenivwithmannichbaseligands |