Reactions of 1-Alkyl-3-phenylbenzimidazolium Salts with Ag<sub>2</sub>O: The Formation of a Ring-Opening Formamide Derivative and a Ag Complex with an <i>N</i>-heterocyclic Carbene Ligand

Reactions of 1-Alkyl-3-phenylbenzimidazolium Salts with Ag<sub>2</sub>O: The Formation of a Ring-Opening Formamide Derivative and a Ag Complex with an <i>N</i>-heterocyclic Carbene Ligand

This study investigated the reactions of 1-alkyl-3-phenylbenzimidazolium salts with Ag<sub>2</sub>O. It was found that the selectivity of the reaction products was influenced by the <i>N</i>-alkyl substituent on the azolium ring. For example, treating 1-methyl-3-phenylbenzimi...

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Bibliographic Details
Main Authors: Satoshi Sakaguchi, Takashi Higashino, Yudai Tasaki, Ryo Ichihara, Tatsuo Yajima
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Inorganics
Subjects:
<i>N</i>-heterocyclic carbene
NHC–silver complexes
NHC–gold complex
hydrolysis
formamide
Online Access:https://www.mdpi.com/2304-6740/13/1/18
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