Factors influencing catalytic behavior of titanium complexes bearing bisphenolate ligands toward ring-opening polymerization of L-lactide and ε-caprolactone

Factors influencing catalytic behavior of titanium complexes bearing bisphenolate ligands toward ring-opening polymerization of L-lactide and ε-caprolactone

A series of titanium complexes bearing substituted diphenolate ligands (RCH(phenolate)2, where R = H, CH3, o-OTs-phenyl, o-F-phenyl, o-OMe-phenyl, 2,4-OMe-phenyl) was synthesized and studied as catalysts for the ring opening polymerization of L-lactide and ε-caprolactone. Ligands were designed to pr...

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Bibliographic Details
Main Authors: M-T. Jiang, S. R. Kosuru, Y. H. Lee, W-Y. Lu, J. K. Vandavasi, Y-C. Lai, M. Y. Chiang, H-Y. Chen
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2018-02-01
Series:eXPRESS Polymer Letters
Subjects:
Biodegradable polymers
polycaprolactone
ring-opening polymerization
polylactide
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0008645&mi=cd
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