Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation

A concept to assess in situ biodegradation of organic contaminants in aquifers is presented. The alteration of the carbon isotope composition of contaminants along the groundwater flow path indicates microbial degradation processes and can be used as an indicator for in situ biodegradation. The Rayl...

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Main Authors: H.H. Richnow, A. Vieth, M. Kastner, M. Gehre, R.U. Meckenstock
Format: Article
Language:English
Published: Wiley 2002-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1100/tsw.2002.210
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author H.H. Richnow
A. Vieth
M. Kastner
M. Gehre
R.U. Meckenstock
author_facet H.H. Richnow
A. Vieth
M. Kastner
M. Gehre
R.U. Meckenstock
author_sort H.H. Richnow
collection DOAJ
description A concept to assess in situ biodegradation of organic contaminants in aquifers is presented. The alteration of the carbon isotope composition of contaminants along the groundwater flow path indicates microbial degradation processes and can be used as an indicator for in situ biodegradation. The Rayleigh equation was applied to calculate the percentage of the in situ biodegradation (B[%]) using the change in the isotopic composition of contaminants (Rt/R0) along the ground water flow path and a kinetic carbon isotope fractionation factor (αC) derived from defined biodegradation experiments in the laboratory. When the groundwater hydrology is known and a representative source concentration (C0) for a groundwater flow path can be determined, the extent of in situ biodegradation can be quantified.
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institution Kabale University
issn 1537-744X
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publishDate 2002-01-01
publisher Wiley
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series The Scientific World Journal
spelling doaj-art-2e3d686a8ec54787a4afab6e8f7c24f02025-08-20T03:55:07ZengWileyThe Scientific World Journal1537-744X2002-01-0121227123410.1100/tsw.2002.210Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ DegradationH.H. Richnow0A. Vieth1M. Kastner2M. Gehre3R.U. Meckenstock4UFZ Centre for Environmental Research Leipzig Halle Ltd., Permoserstr. 15, 04318 Leipzig, GermanyUFZ Centre for Environmental Research Leipzig Halle Ltd., Permoserstr. 15, 04318 Leipzig, GermanyUFZ Centre for Environmental Research Leipzig Halle Ltd., Permoserstr. 15, 04318 Leipzig, GermanyUFZ Centre for Environmental Research Leipzig Halle Ltd., Permoserstr. 15, 04318 Leipzig, GermanyEberhard-Karls University of Tübingen, Center for Applied Geoscience, Sigwartstr. 10, 72076 Tübingen, GermanyA concept to assess in situ biodegradation of organic contaminants in aquifers is presented. The alteration of the carbon isotope composition of contaminants along the groundwater flow path indicates microbial degradation processes and can be used as an indicator for in situ biodegradation. The Rayleigh equation was applied to calculate the percentage of the in situ biodegradation (B[%]) using the change in the isotopic composition of contaminants (Rt/R0) along the ground water flow path and a kinetic carbon isotope fractionation factor (αC) derived from defined biodegradation experiments in the laboratory. When the groundwater hydrology is known and a representative source concentration (C0) for a groundwater flow path can be determined, the extent of in situ biodegradation can be quantified.http://dx.doi.org/10.1100/tsw.2002.210
spellingShingle H.H. Richnow
A. Vieth
M. Kastner
M. Gehre
R.U. Meckenstock
Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation
The Scientific World Journal
title Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation
title_full Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation
title_fullStr Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation
title_full_unstemmed Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation
title_short Isotope Fractionation of Toluene: A Perspective to Characterise Microbial In Situ Degradation
title_sort isotope fractionation of toluene a perspective to characterise microbial in situ degradation
url http://dx.doi.org/10.1100/tsw.2002.210
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AT mkastner isotopefractionationoftolueneaperspectivetocharacterisemicrobialinsitudegradation
AT mgehre isotopefractionationoftolueneaperspectivetocharacterisemicrobialinsitudegradation
AT rumeckenstock isotopefractionationoftolueneaperspectivetocharacterisemicrobialinsitudegradation