An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells

This study presents a new cost-effective metal-free counter electrode (CE) for dye-sensitized solar cells (DSSCs). CE was prepared by doctor blading a hydrophilic carbon (HC) particle on a fluorine-doped tin oxide substrate. Thereafter, HC CE was characterized using X-ray diffraction, profilometry,...

Full description

Saved in:
Bibliographic Details
Main Authors: Mojgan Kouhnavard, Norasikin Ahmad Ludin, Babak Vazifehkhah Ghaffari, Kamaruzzaman Sopian, Norshazlinah Abdul Karim, Mikio Miyake
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2016/5186762
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832553451155881984
author Mojgan Kouhnavard
Norasikin Ahmad Ludin
Babak Vazifehkhah Ghaffari
Kamaruzzaman Sopian
Norshazlinah Abdul Karim
Mikio Miyake
author_facet Mojgan Kouhnavard
Norasikin Ahmad Ludin
Babak Vazifehkhah Ghaffari
Kamaruzzaman Sopian
Norshazlinah Abdul Karim
Mikio Miyake
author_sort Mojgan Kouhnavard
collection DOAJ
description This study presents a new cost-effective metal-free counter electrode (CE) for dye-sensitized solar cells (DSSCs). CE was prepared by doctor blading a hydrophilic carbon (HC) particle on a fluorine-doped tin oxide substrate. Thereafter, HC CE was characterized using X-ray diffraction, profilometry, four-point probe testing, and cyclic voltammetry. A 2 µm thick HC CE revealed a comparable catalytic activity to that of the Pt electrode under the same experimental conditions. DSSC based on HC CE was analyzed and showed Jsc of 6.87 mA/cm2 close to that of DSSC with Pt CE (7.0 mA/cm2). More importantly, DSSC based on HC CE yielded a power conversion efficiency (η) of 2.93% under AM 1.5 irradiation (100 mW/cm2), which was comparable to that of DSSC based on standard Pt CE. These findings suggest that HC CE could be a promising CE for low-cost DSSCs.
format Article
id doaj-art-2dc0858afc1e43f090b01e4b6d593a8b
institution Kabale University
issn 1110-662X
1687-529X
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-2dc0858afc1e43f090b01e4b6d593a8b2025-02-03T05:53:57ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2016-01-01201610.1155/2016/51867625186762An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar CellsMojgan Kouhnavard0Norasikin Ahmad Ludin1Babak Vazifehkhah Ghaffari2Kamaruzzaman Sopian3Norshazlinah Abdul Karim4Mikio Miyake5Malaysia-Japan International Institute of Technology, Universiti Teknologi Malaysia (UTM), 54100 Kuala Lumpur, MalaysiaSolar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor, MalaysiaMalaysia-Japan International Institute of Technology, Universiti Teknologi Malaysia (UTM), 54100 Kuala Lumpur, MalaysiaSolar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor, MalaysiaSolar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor, MalaysiaMalaysia-Japan International Institute of Technology, Universiti Teknologi Malaysia (UTM), 54100 Kuala Lumpur, MalaysiaThis study presents a new cost-effective metal-free counter electrode (CE) for dye-sensitized solar cells (DSSCs). CE was prepared by doctor blading a hydrophilic carbon (HC) particle on a fluorine-doped tin oxide substrate. Thereafter, HC CE was characterized using X-ray diffraction, profilometry, four-point probe testing, and cyclic voltammetry. A 2 µm thick HC CE revealed a comparable catalytic activity to that of the Pt electrode under the same experimental conditions. DSSC based on HC CE was analyzed and showed Jsc of 6.87 mA/cm2 close to that of DSSC with Pt CE (7.0 mA/cm2). More importantly, DSSC based on HC CE yielded a power conversion efficiency (η) of 2.93% under AM 1.5 irradiation (100 mW/cm2), which was comparable to that of DSSC based on standard Pt CE. These findings suggest that HC CE could be a promising CE for low-cost DSSCs.http://dx.doi.org/10.1155/2016/5186762
spellingShingle Mojgan Kouhnavard
Norasikin Ahmad Ludin
Babak Vazifehkhah Ghaffari
Kamaruzzaman Sopian
Norshazlinah Abdul Karim
Mikio Miyake
An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells
International Journal of Photoenergy
title An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells
title_full An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells
title_fullStr An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells
title_full_unstemmed An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells
title_short An Efficient Metal-Free Hydrophilic Carbon as a Counter Electrode for Dye-Sensitized Solar Cells
title_sort efficient metal free hydrophilic carbon as a counter electrode for dye sensitized solar cells
url http://dx.doi.org/10.1155/2016/5186762
work_keys_str_mv AT mojgankouhnavard anefficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT norasikinahmadludin anefficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT babakvazifehkhahghaffari anefficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT kamaruzzamansopian anefficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT norshazlinahabdulkarim anefficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT mikiomiyake anefficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT mojgankouhnavard efficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT norasikinahmadludin efficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT babakvazifehkhahghaffari efficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT kamaruzzamansopian efficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT norshazlinahabdulkarim efficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells
AT mikiomiyake efficientmetalfreehydrophiliccarbonasacounterelectrodefordyesensitizedsolarcells