Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO2 Electroreduction at Low Overpotential

Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO2 Electroreduction at Low Overpotential

Abstract To efficiently capture, activate, and transform small molecules, metalloenzymes have evolved to integrate a well‐organized pocket around the active metal center. Within this cavity, second coordination sphere functionalities are precisely positioned to optimize the rate, selectivity, and en...

Full description

Saved in:
Bibliographic Details
Main Authors: Adrien Smith, Philipp Gotico, Régis Guillot, Stéphane Le Gac, Winfried Leibl, Ally Aukauloo, Bernard Boitrel, Marie Sircoglou, Zakaria Halime
Format: Article
Language:English
Published: Wiley 2025-03-01
Series:Advanced Science
Subjects:
artificial distal pocket
biomimetic
carbon dioxide
electrocatalysis
hydrogen bonding
Online Access:https://doi.org/10.1002/advs.202500482
Tags: Add Tag
No Tags, Be the first to tag this record!

Internet

https://doi.org/10.1002/advs.202500482

Similar Items