Synthese bei Temperaturen unter −80°C

Small differences in free enthalpies of activation (ΔΔG‡) between competing reactions give rise to high selectivity at low enough temperatures. Special techniques are necessary, in order to exploit this effect in preparative-scale conversions. An experimental set-up is described here with which rea...

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Bibliographic Details
Main Authors: Dieter Seebach, August Hidber
Format: Article
Language:deu
Published: Swiss Chemical Society 1983-12-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9600
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