Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications

The aim of this work is to use microcrystalline cellulose (MCC), obtained from kenaf fibers by using eutectic green solvents, to build compostable packaging films by adding them to Poly (butylene adipate-co-terephthalate) (PBAT). In this study, microcrystalline cellulose was incorporated into PBAT c...

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Main Authors: Aatikah Meraj, Ahmad Safwan Ismail, Mohammad Jawaid
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Journal of Natural Fibers
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/15440478.2025.2455978
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author Aatikah Meraj
Ahmad Safwan Ismail
Mohammad Jawaid
author_facet Aatikah Meraj
Ahmad Safwan Ismail
Mohammad Jawaid
author_sort Aatikah Meraj
collection DOAJ
description The aim of this work is to use microcrystalline cellulose (MCC), obtained from kenaf fibers by using eutectic green solvents, to build compostable packaging films by adding them to Poly (butylene adipate-co-terephthalate) (PBAT). In this study, microcrystalline cellulose was incorporated into PBAT composites through melt-mixing, followed by hot pressing at 130°C. PBAT and MCC were produced in various formulations (0.5, 1, 1.5 wt%) to enhance and sustain inherent characteristics of films. The structural, morphological, thermal, and tensile properties of PBAT and microcrystalline cellulose film were examined using X-ray Diffraction, Scanning electron microscope (SEM), Thermal analysis, and Universal Testing Machine. The uniform dispersion of MCC within the PBAT matrix significantly contributes to improved thermal stability, as evidenced by delayed degradation, and enhanced heat resistance. SEM makes it evident that addition of MCC to PBAT influences the surface morphology, with an optimal range promoting mechanical adherence through roughness. However, excessive MCC content leads to imperfections such as cavities, potentially compromising material performance. The inclusion of MCC content enormously raised the tensile modulus of the PBAT/MCC film, increasing its stiffness while tensile strength decreased on addition of MCC in PBAT/MCC formulations. Cellulose film could potentially be used as a biodegradable film in food packaging applications.
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spelling doaj-art-2ae5b6cd1dfe4a2ea292f7bf9a6c0dcb2025-01-29T06:35:15ZengTaylor & Francis GroupJournal of Natural Fibers1544-04781544-046X2025-12-0122110.1080/15440478.2025.2455978Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging ApplicationsAatikah Meraj0Ahmad Safwan Ismail1Mohammad Jawaid2Laboratory of Bio-polymer and its Derivatives, Institute of Tropical Forestry and Forest Products (INTROP) Universiti Putra Malaysia, Serdang, MalaysiaLaboratory of Bio composite Technology, Institute of Tropical Forestry and Forest Products (INTROP) Universiti Putra Malaysia, Serdang, MalaysiaDepartment of Chemical and Petroleum Engineering, United Arab Emirates University (UAEU), Al Ain, United Arab EmiratesThe aim of this work is to use microcrystalline cellulose (MCC), obtained from kenaf fibers by using eutectic green solvents, to build compostable packaging films by adding them to Poly (butylene adipate-co-terephthalate) (PBAT). In this study, microcrystalline cellulose was incorporated into PBAT composites through melt-mixing, followed by hot pressing at 130°C. PBAT and MCC were produced in various formulations (0.5, 1, 1.5 wt%) to enhance and sustain inherent characteristics of films. The structural, morphological, thermal, and tensile properties of PBAT and microcrystalline cellulose film were examined using X-ray Diffraction, Scanning electron microscope (SEM), Thermal analysis, and Universal Testing Machine. The uniform dispersion of MCC within the PBAT matrix significantly contributes to improved thermal stability, as evidenced by delayed degradation, and enhanced heat resistance. SEM makes it evident that addition of MCC to PBAT influences the surface morphology, with an optimal range promoting mechanical adherence through roughness. However, excessive MCC content leads to imperfections such as cavities, potentially compromising material performance. The inclusion of MCC content enormously raised the tensile modulus of the PBAT/MCC film, increasing its stiffness while tensile strength decreased on addition of MCC in PBAT/MCC formulations. Cellulose film could potentially be used as a biodegradable film in food packaging applications.https://www.tandfonline.com/doi/10.1080/15440478.2025.2455978Microcrystalline cellulosebiodegradabletensile propertiesPackagingpoly (butylene adipate-co-terephthalate)微晶纤维素
spellingShingle Aatikah Meraj
Ahmad Safwan Ismail
Mohammad Jawaid
Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications
Journal of Natural Fibers
Microcrystalline cellulose
biodegradable
tensile properties
Packaging
poly (butylene adipate-co-terephthalate)
微晶纤维素
title Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications
title_full Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications
title_fullStr Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications
title_full_unstemmed Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications
title_short Structural, Morphological and Thermal Properties of Kenaf Microcrystalline Cellulose/Poly (Butylene Adipate-Co-Terephthalate) Films for Packaging Applications
title_sort structural morphological and thermal properties of kenaf microcrystalline cellulose poly butylene adipate co terephthalate films for packaging applications
topic Microcrystalline cellulose
biodegradable
tensile properties
Packaging
poly (butylene adipate-co-terephthalate)
微晶纤维素
url https://www.tandfonline.com/doi/10.1080/15440478.2025.2455978
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AT mohammadjawaid structuralmorphologicalandthermalpropertiesofkenafmicrocrystallinecellulosepolybutyleneadipatecoterephthalatefilmsforpackagingapplications