Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes
A transition metal complex, oxovanadium(IV) salen (where salen represents N,N′-bis(salicylidene)ethylenediamine) is immobilized on glassy carbon (GC) electrodes and utilized for electrocatalytic oxidation of cysteine. In presence of oxovanadium(IV) salen, increased oxidation current is observed due...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.1155/2014/316254 |
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| author | Piyush Kumar Sonkar Vellaichamy Ganesan Vijay Rao |
| author_facet | Piyush Kumar Sonkar Vellaichamy Ganesan Vijay Rao |
| author_sort | Piyush Kumar Sonkar |
| collection | DOAJ |
| description | A transition metal complex, oxovanadium(IV) salen (where salen represents N,N′-bis(salicylidene)ethylenediamine) is immobilized on glassy carbon (GC) electrodes and utilized for electrocatalytic oxidation of cysteine. In presence of oxovanadium(IV) salen, increased oxidation current is observed due to the effective oxidation of cysteine by the electrogenerated oxovanadium(V) salen species. The oxidation current linearly varies with the concentration of cysteine from 0.1 to 1.0 mM. The modified electrode has good sensitivity and low limit of detection. These properties make the oxovanadium(IV) salen as an effective electrocatalyst for the determination of cysteine. |
| format | Article |
| id | doaj-art-29a23bf79ebf4c9db0629e1bfcd662b9 |
| institution | Kabale University |
| issn | 2090-3529 2090-3537 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-29a23bf79ebf4c9db0629e1bfcd662b92025-02-03T01:09:23ZengWileyInternational Journal of Electrochemistry2090-35292090-35372014-01-01201410.1155/2014/316254316254Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated ElectrodesPiyush Kumar Sonkar0Vellaichamy Ganesan1Vijay Rao2Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, Uttar Pradesh 221 005, IndiaDepartment of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, Uttar Pradesh 221 005, IndiaDepartment of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, Uttar Pradesh 221 005, IndiaA transition metal complex, oxovanadium(IV) salen (where salen represents N,N′-bis(salicylidene)ethylenediamine) is immobilized on glassy carbon (GC) electrodes and utilized for electrocatalytic oxidation of cysteine. In presence of oxovanadium(IV) salen, increased oxidation current is observed due to the effective oxidation of cysteine by the electrogenerated oxovanadium(V) salen species. The oxidation current linearly varies with the concentration of cysteine from 0.1 to 1.0 mM. The modified electrode has good sensitivity and low limit of detection. These properties make the oxovanadium(IV) salen as an effective electrocatalyst for the determination of cysteine.http://dx.doi.org/10.1155/2014/316254 |
| spellingShingle | Piyush Kumar Sonkar Vellaichamy Ganesan Vijay Rao Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes International Journal of Electrochemistry |
| title | Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes |
| title_full | Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes |
| title_fullStr | Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes |
| title_full_unstemmed | Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes |
| title_short | Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes |
| title_sort | electrocatalytic oxidation and determination of cysteine at oxovanadium iv salen coated electrodes |
| url | http://dx.doi.org/10.1155/2014/316254 |
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