Uranium-stibinidiide, -stibinidene, and -stibido multiple bonds and uranium-nitride formation from multimetallic diuranium-distibene-mediated dinitrogen cleavage

Abstract Although uranium-nitrogen multiple bonding is well developed, there are far fewer uranium-phosphorus and -arsenic multiple bonds, and none for antimony, even in spectroscopic scenarios. Here, we report straightforward syntheses of uranium-stibido, -stibinidiide, -distibene, and -stibinidene...

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Bibliographic Details
Main Authors: Rebecca F. Sheppard, Kevin Dollberg, Nick Michel, John A. Seed, Ashley J. Wooles, Jingzhen Du, Carsten von Hänisch, Stephen T. Liddle
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-61612-5
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