Autoxidation von CuI-Komplexen,VI: Kinetischer Nachweis instabiler Sauerstoffaddukte bei der Oxidation von solvatisiertem Cu+ in Dimethylsulfoxid
The interaction between Cu+ and O2 has been studied in DMSO. The experimental rate law is given by −d[O2]/dt = kter [Cu+]2[O2](1 + kH[H+]) with kter = (7.1 ± 0.4)・103 M-2s-1and kH = 190 ± 12 M-1 at 25° and l=0.1.The redox-stoichiometry O2 : Cu+ is strictly 1:2 but less than one third of the metal...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1974-02-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9126 |
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