Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water

The adsorption mechanism of the removal of lead from water by using carboxylic functional group (COOH) functionalized on the surface of carbon nanotubes was investigated. Four independent variables including pH, CNTs dosage, contact time, and agitation speed were carried out to determine the influe...

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Main Authors: Muataz Ali Atieh, Omer Yehya Bakather, Bassam Al-Tawbini, Alaadin A. Bukhari, Faraj Ahmad Abuilaiwi, Mohamed B. Fettouhi
Format: Article
Language:English
Published: Wiley 2010-01-01
Series:Bioinorganic Chemistry and Applications
Online Access:http://dx.doi.org/10.1155/2010/603978
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author Muataz Ali Atieh
Omer Yehya Bakather
Bassam Al-Tawbini
Alaadin A. Bukhari
Faraj Ahmad Abuilaiwi
Mohamed B. Fettouhi
author_facet Muataz Ali Atieh
Omer Yehya Bakather
Bassam Al-Tawbini
Alaadin A. Bukhari
Faraj Ahmad Abuilaiwi
Mohamed B. Fettouhi
author_sort Muataz Ali Atieh
collection DOAJ
description The adsorption mechanism of the removal of lead from water by using carboxylic functional group (COOH) functionalized on the surface of carbon nanotubes was investigated. Four independent variables including pH, CNTs dosage, contact time, and agitation speed were carried out to determine the influence of these parameters on the adsorption capacity of the lead from water. The morphology of the synthesized multiwall carbon nanotubes (MWCNTs) was characterized by using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) in order to measure the diameter and the length of the CNTs. The diameters of the carbon nanotubes were varied from 20 to 40 nm with average diameter at 24 nm and 10 micrometer in length. Results of the study showed that 100% of lead was removed by using COOH-MCNTs at pH 7, 150 rpm, and 2 hours. These high removal efficiencies were likely attributed to the strong affinity of lead to the physical and chemical properties of the CNTs. The adsorption isotherms plots were well fitted with experimental data.
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institution Kabale University
issn 1565-3633
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language English
publishDate 2010-01-01
publisher Wiley
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series Bioinorganic Chemistry and Applications
spelling doaj-art-1eb9a26b4cd44d50bb276bd8375cc1712025-02-03T05:46:49ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2010-01-01201010.1155/2010/603978603978Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from WaterMuataz Ali Atieh0Omer Yehya Bakather1Bassam Al-Tawbini2Alaadin A. Bukhari3Faraj Ahmad Abuilaiwi4Mohamed B. Fettouhi5Chemical Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaChemical Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaCenter of Research Excellences in Nanotechnology, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaResearch Institute, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaCenter of Research Excellences in Nanotechnology, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaChemistry Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaThe adsorption mechanism of the removal of lead from water by using carboxylic functional group (COOH) functionalized on the surface of carbon nanotubes was investigated. Four independent variables including pH, CNTs dosage, contact time, and agitation speed were carried out to determine the influence of these parameters on the adsorption capacity of the lead from water. The morphology of the synthesized multiwall carbon nanotubes (MWCNTs) was characterized by using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) in order to measure the diameter and the length of the CNTs. The diameters of the carbon nanotubes were varied from 20 to 40 nm with average diameter at 24 nm and 10 micrometer in length. Results of the study showed that 100% of lead was removed by using COOH-MCNTs at pH 7, 150 rpm, and 2 hours. These high removal efficiencies were likely attributed to the strong affinity of lead to the physical and chemical properties of the CNTs. The adsorption isotherms plots were well fitted with experimental data.http://dx.doi.org/10.1155/2010/603978
spellingShingle Muataz Ali Atieh
Omer Yehya Bakather
Bassam Al-Tawbini
Alaadin A. Bukhari
Faraj Ahmad Abuilaiwi
Mohamed B. Fettouhi
Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water
Bioinorganic Chemistry and Applications
title Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water
title_full Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water
title_fullStr Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water
title_full_unstemmed Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water
title_short Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water
title_sort effect of carboxylic functional group functionalized on carbon nanotubes surface on the removal of lead from water
url http://dx.doi.org/10.1155/2010/603978
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