Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment

A breakthrough in superabsorbent hydrogel (SAH) preparation was studied in the current issue by blending potato starch and acrylic acid for wastewater treatment. Gamma irradiation source (60Co irradiation) was used to irradiate SAH from 1 to 10 kGy dose at room temperature (~27°C). The swelling rati...

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Main Authors: Md. Owaleur Rahman, Md. Abdul Halim, Anjan Deb, Shafi Ahmed, Md. Wasikur Rahman, N. C. Dafader, S. M. Nur Alam, Shahjalal Khandaker, Md. Jahangir Alam
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Polymer Technology
Online Access:http://dx.doi.org/10.1155/2022/8405230
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author Md. Owaleur Rahman
Md. Abdul Halim
Anjan Deb
Shafi Ahmed
Md. Wasikur Rahman
N. C. Dafader
S. M. Nur Alam
Shahjalal Khandaker
Md. Jahangir Alam
author_facet Md. Owaleur Rahman
Md. Abdul Halim
Anjan Deb
Shafi Ahmed
Md. Wasikur Rahman
N. C. Dafader
S. M. Nur Alam
Shahjalal Khandaker
Md. Jahangir Alam
author_sort Md. Owaleur Rahman
collection DOAJ
description A breakthrough in superabsorbent hydrogel (SAH) preparation was studied in the current issue by blending potato starch and acrylic acid for wastewater treatment. Gamma irradiation source (60Co irradiation) was used to irradiate SAH from 1 to 10 kGy dose at room temperature (~27°C). The swelling ratio, water absorption, equilibrium water content, and gel fraction properties of the hydrogel were investigated. The as-prepared hydrogel treated with KOH (THG) showed excellent absorption capacity but less mechanical stability compared to untreated hydrogel (UHG). The gel fraction of treated SAH was slightly lower in methanol, but the utmost in water at 5 kGy infers the proper grafting of SAH at this point. The prepared SAH was characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) to investigate the surface morphology and molecular interaction, respectively. Moreover, this study’s focal point is to propose an alternative method to remove chromium and methylene blue by SAH from industrial wastewater. The Cr adsorption capacity of UHG was higher than that of THG because the proton’s replacement is easier than that of K by Cr. On the other hand, THG was found to be more efficient in removing methylene blue from industrial wastewater due to the presence of an easily ionized group (–COOK) in SAH. Therefore, the hydrogel can be proposed as a potential superabsorbent to remove heavy metals and organic dyes from industrial wastewater.
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series Advances in Polymer Technology
spelling doaj-art-1e8c0145ff624bdcb2ae04212d886d1c2025-02-03T00:59:02ZengWileyAdvances in Polymer Technology1098-23292022-01-01202210.1155/2022/8405230Modification of Superabsorbent Hydrogels for Industrial Wastewater TreatmentMd. Owaleur Rahman0Md. Abdul Halim1Anjan Deb2Shafi Ahmed3Md. Wasikur Rahman4N. C. Dafader5S. M. Nur Alam6Shahjalal Khandaker7Md. Jahangir Alam8Department of Chemical EngineeringDepartment of Chemical EngineeringDepartment of Chemical EngineeringDepartment of Agro Product Processing TechnologyDepartment of Chemical EngineeringNuclear and Radiation Chemistry DivisionDepartment of Chemical EngineeringDepartment of Textile EngineeringDepartment of Chemical EngineeringA breakthrough in superabsorbent hydrogel (SAH) preparation was studied in the current issue by blending potato starch and acrylic acid for wastewater treatment. Gamma irradiation source (60Co irradiation) was used to irradiate SAH from 1 to 10 kGy dose at room temperature (~27°C). The swelling ratio, water absorption, equilibrium water content, and gel fraction properties of the hydrogel were investigated. The as-prepared hydrogel treated with KOH (THG) showed excellent absorption capacity but less mechanical stability compared to untreated hydrogel (UHG). The gel fraction of treated SAH was slightly lower in methanol, but the utmost in water at 5 kGy infers the proper grafting of SAH at this point. The prepared SAH was characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) to investigate the surface morphology and molecular interaction, respectively. Moreover, this study’s focal point is to propose an alternative method to remove chromium and methylene blue by SAH from industrial wastewater. The Cr adsorption capacity of UHG was higher than that of THG because the proton’s replacement is easier than that of K by Cr. On the other hand, THG was found to be more efficient in removing methylene blue from industrial wastewater due to the presence of an easily ionized group (–COOK) in SAH. Therefore, the hydrogel can be proposed as a potential superabsorbent to remove heavy metals and organic dyes from industrial wastewater.http://dx.doi.org/10.1155/2022/8405230
spellingShingle Md. Owaleur Rahman
Md. Abdul Halim
Anjan Deb
Shafi Ahmed
Md. Wasikur Rahman
N. C. Dafader
S. M. Nur Alam
Shahjalal Khandaker
Md. Jahangir Alam
Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment
Advances in Polymer Technology
title Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment
title_full Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment
title_fullStr Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment
title_full_unstemmed Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment
title_short Modification of Superabsorbent Hydrogels for Industrial Wastewater Treatment
title_sort modification of superabsorbent hydrogels for industrial wastewater treatment
url http://dx.doi.org/10.1155/2022/8405230
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