[MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization
In the present research, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were first prepared through simple stepwise in situ techniques: sol-gel technique and solution-cast technique. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/Ti...
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| Format: | Article |
| Language: | English |
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Wiley
2016-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2016/9838067 |
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| _version_ | 1832563829499756544 |
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| author | Oon Lee Kang Azizan Ahmad Nur Hasyareeda Hassan Usman Ali Rana |
| author_facet | Oon Lee Kang Azizan Ahmad Nur Hasyareeda Hassan Usman Ali Rana |
| author_sort | Oon Lee Kang |
| collection | DOAJ |
| description | In the present research, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were first prepared through simple stepwise in situ techniques: sol-gel technique and solution-cast technique. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were then characterized through different experimental techniques. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited significant structural changes upon different salt concentrations. In the present investigation, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had attained maximum ionic conductivities (σ~10-7 S/cm at ambient temperature; 10−4 S/cm at 100°C) upon 25 wt.% salt insertion. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited distinct conduction mechanisms in similar experimental configuration. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited different stability characteristics over certain operational condition. |
| format | Article |
| id | doaj-art-1e7ba58a2199470e8ed64d9dc3cf5284 |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-1e7ba58a2199470e8ed64d9dc3cf52842025-02-03T01:12:24ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/98380679838067[MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and CharacterizationOon Lee Kang0Azizan Ahmad1Nur Hasyareeda Hassan2Usman Ali Rana3Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaFaculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaFaculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaSustainable Energy Technologies (SET) Center, King Saud University, P.O. Box 800, Riyadh 11421, Saudi ArabiaIn the present research, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were first prepared through simple stepwise in situ techniques: sol-gel technique and solution-cast technique. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes were then characterized through different experimental techniques. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited significant structural changes upon different salt concentrations. In the present investigation, [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had attained maximum ionic conductivities (σ~10-7 S/cm at ambient temperature; 10−4 S/cm at 100°C) upon 25 wt.% salt insertion. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited distinct conduction mechanisms in similar experimental configuration. [MG49-LiClO4]:[HNO3-THF/TiO2-SiO2] and [MG49-LiClO4]:[ClHNO2-THF/TiO2-SiO2] polymer electrolytes had exhibited different stability characteristics over certain operational condition.http://dx.doi.org/10.1155/2016/9838067 |
| spellingShingle | Oon Lee Kang Azizan Ahmad Nur Hasyareeda Hassan Usman Ali Rana [MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization International Journal of Polymer Science |
| title | [MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization |
| title_full | [MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization |
| title_fullStr | [MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization |
| title_full_unstemmed | [MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization |
| title_short | [MG49-LiClO4]:[TiO2-SiO2] Polymer Electrolytes: In Situ Preparation and Characterization |
| title_sort | mg49 liclo4 tio2 sio2 polymer electrolytes in situ preparation and characterization |
| url | http://dx.doi.org/10.1155/2016/9838067 |
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