Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values
The inhibitory effect of glycerol on copper corrosion in aerated NaCl (0.5 M) solutions at three pH values (4, 7, and 10) was evaluated. Inhibition efficiency was assessed with conventional electrochemical techniques: open circuit potential, potentiodynamic polarization, and electrochemical impedanc...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2014/396405 |
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| author | Santos Lorenzo Chi-Ucán Andrea Castillo-Atoche Pedro Castro Borges José Antonio Manzanilla-Cano Gerardo González-García Rodrigo Patiño Luis Díaz-Ballote |
| author_facet | Santos Lorenzo Chi-Ucán Andrea Castillo-Atoche Pedro Castro Borges José Antonio Manzanilla-Cano Gerardo González-García Rodrigo Patiño Luis Díaz-Ballote |
| author_sort | Santos Lorenzo Chi-Ucán |
| collection | DOAJ |
| description | The inhibitory effect of glycerol on copper corrosion in aerated NaCl (0.5 M) solutions at three pH values (4, 7, and 10) was evaluated. Inhibition efficiency was assessed with conventional electrochemical techniques: open circuit potential, potentiodynamic polarization, and electrochemical impedance analysis. Glycerol reduced the corrosion rate of copper in NaCl solutions. The best inhibition effect (η≈83%) was produced in alkaline (pH 10) chloride media. This effect can be ascribed to increased viscosity and the presence of copper-glycerol complexes. |
| format | Article |
| id | doaj-art-1744904e813545eebfc6ba726ca97f95 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-1744904e813545eebfc6ba726ca97f952025-02-03T06:12:42ZengWileyJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/396405396405Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH ValuesSantos Lorenzo Chi-Ucán0Andrea Castillo-Atoche1Pedro Castro Borges2José Antonio Manzanilla-Cano3Gerardo González-García4Rodrigo Patiño5Luis Díaz-Ballote6Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida, Antigua Carretera a Progreso Km. 6, 97310 Mérida, YUC, MexicoDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida, Antigua Carretera a Progreso Km. 6, 97310 Mérida, YUC, MexicoDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida, Antigua Carretera a Progreso Km. 6, 97310 Mérida, YUC, MexicoLaboratorio de Electroquímica Analítica, Facultad de Química, Universidad Autónoma de Yucatán, Calle 41 No. 421 entre 26 y 28, Colonia Industrial, 97150 Mérida, YUC, MexicoDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida, Antigua Carretera a Progreso Km. 6, 97310 Mérida, YUC, MexicoDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida, Antigua Carretera a Progreso Km. 6, 97310 Mérida, YUC, MexicoDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida, Antigua Carretera a Progreso Km. 6, 97310 Mérida, YUC, MexicoThe inhibitory effect of glycerol on copper corrosion in aerated NaCl (0.5 M) solutions at three pH values (4, 7, and 10) was evaluated. Inhibition efficiency was assessed with conventional electrochemical techniques: open circuit potential, potentiodynamic polarization, and electrochemical impedance analysis. Glycerol reduced the corrosion rate of copper in NaCl solutions. The best inhibition effect (η≈83%) was produced in alkaline (pH 10) chloride media. This effect can be ascribed to increased viscosity and the presence of copper-glycerol complexes.http://dx.doi.org/10.1155/2014/396405 |
| spellingShingle | Santos Lorenzo Chi-Ucán Andrea Castillo-Atoche Pedro Castro Borges José Antonio Manzanilla-Cano Gerardo González-García Rodrigo Patiño Luis Díaz-Ballote Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values Journal of Chemistry |
| title | Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values |
| title_full | Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values |
| title_fullStr | Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values |
| title_full_unstemmed | Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values |
| title_short | Inhibition Effect of Glycerol on the Corrosion of Copper in NaCl Solutions at Different pH Values |
| title_sort | inhibition effect of glycerol on the corrosion of copper in nacl solutions at different ph values |
| url | http://dx.doi.org/10.1155/2014/396405 |
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