Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite

Electrorefining is a key step in pyroprocessing. The solid cathode processing is necessary to separate the salt from the cathode of the electrorefiner since the uranium deposit in a solid cathode contains electrolyte salt. Moreover, it is very important to increase the throughput of the salt separat...

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Main Authors: Sang Woon Kwon, Si Woo Park, Sung Jai Lee
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Science and Technology of Nuclear Installations
Online Access:http://dx.doi.org/10.1155/2020/8866234
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author Sang Woon Kwon
Si Woo Park
Sung Jai Lee
author_facet Sang Woon Kwon
Si Woo Park
Sung Jai Lee
author_sort Sang Woon Kwon
collection DOAJ
description Electrorefining is a key step in pyroprocessing. The solid cathode processing is necessary to separate the salt from the cathode of the electrorefiner since the uranium deposit in a solid cathode contains electrolyte salt. Moreover, it is very important to increase the throughput of the salt separation system due to the high uranium content of the spent nuclear fuel and high salt fraction of uranium dendrites. Therefore, in this study, the effect of deposit on the evaporation of the adhered salt in a uranium deposit was investigated by using the samples of salt in the uranium deposit and salt in the deposit of the surrogate material for the effective separation of the salt. It was found that the salt evaporation rate is dependent on the deposit type and bulk density in the crucible. Additionally, the evaporation rate was found to be lower when the deposit structure is complex; the rate also decreases as the bulk density of the deposit is increased owing to the retardation of the salt vapour transport process. It was concluded that the mass transfer of the salt vapour is an important parameter for the achievement of a high throughput performance in the salt distillation process.
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spelling doaj-art-0f12bf05d4b847f0a2ff669daec899b42025-02-03T01:04:05ZengWileyScience and Technology of Nuclear Installations1687-60751687-60832020-01-01202010.1155/2020/88662348866234Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium DendriteSang Woon Kwon0Si Woo Park1Sung Jai Lee2Korea Atomic Energy Research Institute, 989-111 Daedukdaero, Yuseong-gu, Daejeon 34057, Republic of KoreaWonjin Co., 17 Nonggong-gil, Boseong-gun, Jeollanamdo 59443, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedukdaero, Yuseong-gu, Daejeon 34057, Republic of KoreaElectrorefining is a key step in pyroprocessing. The solid cathode processing is necessary to separate the salt from the cathode of the electrorefiner since the uranium deposit in a solid cathode contains electrolyte salt. Moreover, it is very important to increase the throughput of the salt separation system due to the high uranium content of the spent nuclear fuel and high salt fraction of uranium dendrites. Therefore, in this study, the effect of deposit on the evaporation of the adhered salt in a uranium deposit was investigated by using the samples of salt in the uranium deposit and salt in the deposit of the surrogate material for the effective separation of the salt. It was found that the salt evaporation rate is dependent on the deposit type and bulk density in the crucible. Additionally, the evaporation rate was found to be lower when the deposit structure is complex; the rate also decreases as the bulk density of the deposit is increased owing to the retardation of the salt vapour transport process. It was concluded that the mass transfer of the salt vapour is an important parameter for the achievement of a high throughput performance in the salt distillation process.http://dx.doi.org/10.1155/2020/8866234
spellingShingle Sang Woon Kwon
Si Woo Park
Sung Jai Lee
Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite
Science and Technology of Nuclear Installations
title Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite
title_full Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite
title_fullStr Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite
title_full_unstemmed Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite
title_short Effect of Deposit on the Evaporation Rate of Adhered Salt in Uranium Dendrite
title_sort effect of deposit on the evaporation rate of adhered salt in uranium dendrite
url http://dx.doi.org/10.1155/2020/8866234
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