Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays

Well-aligned TiO2 nanotube arrays were fabricated by anodizing Ti foil in viscous F− containing organic electrolytes, and the crystal structure and morphology of the TiO2 nanotube array were characterized and analyzed by XRD, SEM, and TEM, respectively. The photocatalytic activity of the TiO2 nanotu...

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Main Authors: Xiaomeng Wu, Zhaohui Huang, Yangai Liu, Minghao Fang
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/832516
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author Xiaomeng Wu
Zhaohui Huang
Yangai Liu
Minghao Fang
author_facet Xiaomeng Wu
Zhaohui Huang
Yangai Liu
Minghao Fang
author_sort Xiaomeng Wu
collection DOAJ
description Well-aligned TiO2 nanotube arrays were fabricated by anodizing Ti foil in viscous F− containing organic electrolytes, and the crystal structure and morphology of the TiO2 nanotube array were characterized and analyzed by XRD, SEM, and TEM, respectively. The photocatalytic activity of the TiO2 nanotube arrays was evaluated in the photocatalytic (PC) and photoelectrocatalytic (PEC) degradation of methylene blue (MB) dye in different supporting solutions. The excellent performance of ca. 97% for color removal was reached after 90 min in the PEC process compared to that of PC process which indicates that a certain external potential bias favors the promotion of the electrode reaction rate on TiO2 nanotube array when it is under illumination. In addition, it is found that PEC process conducted in supporting solutions with low pH and containing Cl− is also beneficial to accelerate the degradation rate of MB.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2012-01-01
publisher Wiley
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series International Journal of Photoenergy
spelling doaj-art-0e0a1f2d9e72464981a438dfe1f7f7902025-02-03T01:30:13ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/832516832516Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube ArraysXiaomeng Wu0Zhaohui Huang1Yangai Liu2Minghao Fang3School of Materials Science and Technology, China University of Geosciences-Beijing, Beijing 100083, ChinaSchool of Materials Science and Technology, China University of Geosciences-Beijing, Beijing 100083, ChinaSchool of Materials Science and Technology, China University of Geosciences-Beijing, Beijing 100083, ChinaSchool of Materials Science and Technology, China University of Geosciences-Beijing, Beijing 100083, ChinaWell-aligned TiO2 nanotube arrays were fabricated by anodizing Ti foil in viscous F− containing organic electrolytes, and the crystal structure and morphology of the TiO2 nanotube array were characterized and analyzed by XRD, SEM, and TEM, respectively. The photocatalytic activity of the TiO2 nanotube arrays was evaluated in the photocatalytic (PC) and photoelectrocatalytic (PEC) degradation of methylene blue (MB) dye in different supporting solutions. The excellent performance of ca. 97% for color removal was reached after 90 min in the PEC process compared to that of PC process which indicates that a certain external potential bias favors the promotion of the electrode reaction rate on TiO2 nanotube array when it is under illumination. In addition, it is found that PEC process conducted in supporting solutions with low pH and containing Cl− is also beneficial to accelerate the degradation rate of MB.http://dx.doi.org/10.1155/2012/832516
spellingShingle Xiaomeng Wu
Zhaohui Huang
Yangai Liu
Minghao Fang
Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays
International Journal of Photoenergy
title Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays
title_full Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays
title_fullStr Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays
title_full_unstemmed Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays
title_short Investigation on the Photoelectrocatalytic Activity of Well-Aligned TiO2 Nanotube Arrays
title_sort investigation on the photoelectrocatalytic activity of well aligned tio2 nanotube arrays
url http://dx.doi.org/10.1155/2012/832516
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AT yangailiu investigationonthephotoelectrocatalyticactivityofwellalignedtio2nanotubearrays
AT minghaofang investigationonthephotoelectrocatalyticactivityofwellalignedtio2nanotubearrays