Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature
A simple, general and efficient method has been developed for the conversion of aldehydes to 1,1-diacetates using acetic anhydride, a catalytic amount of non commercial Keggin heteropolyacid (H6 PalMo11O40) (1% mol) in solvent free conditions at room temperature. Aromatic and aliphatic, simple an...
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| Format: | Article |
| Language: | English |
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Wiley
2007-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2007/313414 |
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| author | G. Romanelli P. Dimitroff P. Vázquez J. C. Autino |
| author_facet | G. Romanelli P. Dimitroff P. Vázquez J. C. Autino |
| author_sort | G. Romanelli |
| collection | DOAJ |
| description | A simple, general and efficient method has been developed for the conversion of aldehydes to 1,1-diacetates using acetic anhydride, a catalytic amount of non commercial Keggin heteropolyacid (H6 PalMo11O40) (1% mol) in solvent free conditions at room temperature. Aromatic and aliphatic, simple and conjugated aldehydes were protected with excellent yields. |
| format | Article |
| id | doaj-art-00d7a1416c894a9684fa39c7aeca11b2 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2007-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-00d7a1416c894a9684fa39c7aeca11b22025-02-03T01:10:52ZengWileyE-Journal of Chemistry0973-49452090-98102007-01-0141838910.1155/2007/313414Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room TemperatureG. Romanelli0P. Dimitroff1P. Vázquez2J. C. Autino3Centro de Investigación y Desarrollo en Ciencias Aplicadas, Dr. Jorge Ronco (CINDECA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata-CONICET. Calle 47 Nro 257 (1900) La Plata, ArgentinaCentro de Investigación y Desarrollo en Ciencias Aplicadas, Dr. Jorge Ronco (CINDECA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata-CONICET. Calle 47 Nro 257 (1900) La Plata, ArgentinaCentro de Investigación y Desarrollo en Ciencias Aplicadas, Dr. Jorge Ronco (CINDECA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata-CONICET. Calle 47 Nro 257 (1900) La Plata, ArgentinaLaboratorio de Estudio de Compuestos Orgánicos (LADECOR), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Calles 47 y 115 (1900) La Plata, ArgentinaA simple, general and efficient method has been developed for the conversion of aldehydes to 1,1-diacetates using acetic anhydride, a catalytic amount of non commercial Keggin heteropolyacid (H6 PalMo11O40) (1% mol) in solvent free conditions at room temperature. Aromatic and aliphatic, simple and conjugated aldehydes were protected with excellent yields.http://dx.doi.org/10.1155/2007/313414 |
| spellingShingle | G. Romanelli P. Dimitroff P. Vázquez J. C. Autino Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature E-Journal of Chemistry |
| title | Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature |
| title_full | Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature |
| title_fullStr | Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature |
| title_full_unstemmed | Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature |
| title_short | Chemoselective Preparation of 1,1-Diacetates from Aldehydes, Mediated by a Keggin Heteropolyacid Under Solvent Free Conditions at Room Temperature |
| title_sort | chemoselective preparation of 1 1 diacetates from aldehydes mediated by a keggin heteropolyacid under solvent free conditions at room temperature |
| url | http://dx.doi.org/10.1155/2007/313414 |
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