Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex
Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) complex has been synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal and molecular structure of the title compound has been determined from single crystal X-ray diffraction data. It crystallizes in...
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| Format: | Article |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/594810 |
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| author | Hakan Arslan Ulrich Flörke Demet Sezgin Mansuroglu |
| author_facet | Hakan Arslan Ulrich Flörke Demet Sezgin Mansuroglu |
| author_sort | Hakan Arslan |
| collection | DOAJ |
| description | Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) complex has been synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal and molecular structure of the title compound has been determined from single crystal X-ray diffraction data. It crystallizes in the triclinic space group P-1, with a = 13.046(2) Å, b = 13.135(2) Å, c = 13.179(2) Å, α= 67.083(4)°, β= 67.968(4)°, γ = 84.756(4)° and Dcalc =1.330 g/cm3 for Z = 2. The crystal structure confirms that the complex is a mononuclear copper(II) complex and the 2,2-diphenyl-N-(di-n-propyl-carbamothioyl)acetamide ligand is a bidentate chelating ligand, coordinating to the copper atom through the thiocarbonyl and carbonyl groups. This coordination has a slightly distorted square-planar geometry (O1-Cu1-O2: 86.48(11)°, O1-Cu1-S1: 93.85(9)°, O2-Cu1-S2: 94.20(9)° and S1-Cu1-S2: 91.21(4)°). The title molecule shows a cis-arrangement and C–O, C–S and C–N bond lengths of the complex suggest considerable electronic delocalization in the chelate rings. |
| format | Article |
| id | doaj-art-009172c0cb98411a8d22bd735e45dab0 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-009172c0cb98411a8d22bd735e45dab02025-02-03T05:50:11ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018S1S455S46110.1155/2011/594810Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) ComplexHakan Arslan0Ulrich Flörke1Demet Sezgin Mansuroglu2Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, TurkeyDepartment of Chemistry, University of Paderborn, Paderborn, D-33098, GermanyDepartment of Chemistry, Faculty of Pharmacy, Mersin University, Mersin, TR-33169, TurkeyBis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) complex has been synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal and molecular structure of the title compound has been determined from single crystal X-ray diffraction data. It crystallizes in the triclinic space group P-1, with a = 13.046(2) Å, b = 13.135(2) Å, c = 13.179(2) Å, α= 67.083(4)°, β= 67.968(4)°, γ = 84.756(4)° and Dcalc =1.330 g/cm3 for Z = 2. The crystal structure confirms that the complex is a mononuclear copper(II) complex and the 2,2-diphenyl-N-(di-n-propyl-carbamothioyl)acetamide ligand is a bidentate chelating ligand, coordinating to the copper atom through the thiocarbonyl and carbonyl groups. This coordination has a slightly distorted square-planar geometry (O1-Cu1-O2: 86.48(11)°, O1-Cu1-S1: 93.85(9)°, O2-Cu1-S2: 94.20(9)° and S1-Cu1-S2: 91.21(4)°). The title molecule shows a cis-arrangement and C–O, C–S and C–N bond lengths of the complex suggest considerable electronic delocalization in the chelate rings.http://dx.doi.org/10.1155/2011/594810 |
| spellingShingle | Hakan Arslan Ulrich Flörke Demet Sezgin Mansuroglu Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex E-Journal of Chemistry |
| title | Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex |
| title_full | Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex |
| title_fullStr | Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex |
| title_full_unstemmed | Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex |
| title_short | Crystal and Molecular Structure of Bis(2,2-diphenyl-N-(di-n-propylcarbamothioyl) acetamido)copper(II) Complex |
| title_sort | crystal and molecular structure of bis 2 2 diphenyl n di n propylcarbamothioyl acetamido copper ii complex |
| url | http://dx.doi.org/10.1155/2011/594810 |
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