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Intrinsically stretchable fully π-conjugated polymers with inter-aggregate capillary interaction for deep-blue flexible inkjet-printed light-emitting diodes
Published 2025-01-01“…The loose rod-shaped stacking of asymmetric conjugated polymers chain in the precursor printed ink makes it easier to improve the intrinsic stretchability of inkjet-printed films. More interestingly, the anisotropic shape rod-like aggregate of conjugated polymers chains also induced a strong capillary interaction and further suppressed the coffee-ring effect, which is more likely to allow for uniform deposition during printed processing and form uniform printed films.…”
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Conjugated Ladder Polymers: Unique Organic π-Conjugated Materials for Optoelectronics, Transistors, and Energy Harvesting and Storage
Published 2025-01-01“…Conjugated ladder polymers (cLPs) are polymers consisting of continuous fused aromatic rings with π conjugation along their backbone. This unique structure imparts cLPs with exceptional thermal, mechanical, and electrochemical stability, as well as notable optical and electrical properties due to their rigid, planar structures. …”
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[(2-Dimesitylboryl)phenyl]ethynyl-Substituted [2.2]Paracyclophane Exhibiting Circularly Polarized Luminescence in Both Solution and Solid-State
Published 2025-01-01“…In addition, this compound can emit strong blue fluorescence in the solid state with quantum yields that are even much higher than in solution (<i>Φ</i><sub>F</sub> up to 0.64 in powder and spin-coated film). Moreover, the enantiomeric forms of <b><i>m</i>-BPhANPh<sub>2</sub>-Cp</b> can show strong CPL signals in both dilute solution and solid state with |<i>g</i><sub>lum</sub>|s up to 9.6 × 10<sup>−3</sup> and 5.4 × 10<sup>−3</sup>, respectively. …”
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