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    The Effect of Alkyl Substituents on the Formation and Structure of Homochiral (<i>R</i>*,<i>R</i>*)-[R<sub>2</sub>Ga(<i>µ</i>-OCH(Me)CO<sub>2</sub>R′)]<sub>2</sub> Species—Towards the Factors Controlling the Stereoselectivity of Dialkylgallium Alkoxides in the Ring-Opening Polymerization of <i>rac</i>-Lactide by Magdalena Kaźmierczak, Łukasz Dobrzycki, Maciej Dranka, Paweł Horeglad

    Published 2025-01-01
    “…Building on our previous studies, which have demonstrated that homochiral propagating species—(<i>R</i>*,<i>R</i>*)-[Me<sub>2</sub>Ga(<i>µ</i>-OCH(Me)CO<sub>2</sub>R)]<sub>2</sub>—were crucial for the heteroselectivity of [Me<sub>2</sub>Ga(<i>µ</i>-OCH(Me)CO<sub>2</sub>Me)]<sub>2</sub> in the ring-opening polymerization (ROP) of racemic lactide (<i>rac</i>-LA), we have investigated the effect of alkyl groups on the structure and catalytic properties of dialkylgallium alkoxides in the ROP of <i>rac</i>-LA. …”
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