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Published 2006-01-01“…Catalytic activity of mesoporous <mml:math alttext="${ext{TiO}}_{ext{2}} $"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mtext>2</mml:mtext> </mml:msub> </mml:mrow> </mml:math> and <mml:math alttext="${{{ext{TiO}}_{ext{2}} } mathord{left/ {vphantom {{{ext{TiO}}_{ext{2}} } {{ext{ZrO}}_2 }}} ight. kern- ulldelimiterspace} {{ext{ZrO}}_2 }}$"> <mml:mrow> <mml:mrow> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mtext>2</mml:mtext> </mml:msub> </mml:mrow> <mml:mo>/</mml:mo> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>ZrO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:mrow> </mml:mrow> </mml:math> (<mml:math alttext="$5$"> <mml:mtext>5</mml:mtext> </mml:math>–50% of <mml:math alttext="${ext{ZrO}}_{ext{2}} $"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>ZrO</mml:mtext> </mml:mrow> <mml:mtext>2</mml:mtext> </mml:msub> </mml:mrow> </mml:math>) films in the processes of <mml:math alttext="${ext{Cr}}^{{ext{VI}}} $"> <mml:mrow> <mml:msup> <mml:mrow> <mml:mtext>Cr</mml:mtext> </mml:mrow> <mml:mrow> <mml:mtext>VI</mml:mtext> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> to <mml:math alttext="${ext{Cr}}^{{ext{III}}} $"> <mml:mrow> <mml:msup> <mml:mrow> <mml:mtext>Cr</mml:mtext> </mml:mrow> <mml:mrow> <mml:mtext>III</mml:mtext> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> photoreduction and 2,4-dinitroaniline photooxidation correlates with crystalline size and growth with increasing of specific surface area of the samples.…”
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