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121
Electrocatalytic and Photocatalytic N<sub>2</sub> Fixation Using Carbon Catalysts
Published 2025-01-01“…These properties significantly enhance electrocatalytic and photocatalytic nitrogen reduction reaction (NRR) activity. While transition metal-based catalysts have solved the kinetic constraints to activate nitrogen bonds via the donation-back-π approach, there is a problem: the d-orbital electrons of these transition metal atoms tend to generate H-metal bonds, inadvertently amplifying unwanted HER. …”
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122
Defect state enhanced nonlinear absorption and optical limiting behaviour of erbium doped silver molybdate nanostructures
Published 2025-01-01“…Abstract Transition metal based optical limiting materials have garnered significant attention due their crucial role in protecting sensitive optical system from high intense laser damage. …”
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123
Recent insights into the transformative role of Graphene‐based/TiO2 electron transport layers for perovskite solar cells
Published 2025-01-01“…However, in practice, they face practical limitations due to suboptimal electron transport, inadequate hole‐suppression, photocatalytic instability, and susceptibility to other environmental factors. Many transition metal oxides such as ZnO and TiO2 have important excitonic properties that make them good electron transport layer (ETL) materials in PSCs. …”
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124
Studies of Metal Organic Networks via M-Polynomial-Based Topological Indices
Published 2022-01-01“…In this article, we study transition metal tetra-cyano-benzene organic networks by computing their M-polynomials and various topological indices (TIs). …”
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125
Using Statistical Analysis as an Additional Tool in Porous Solid Characterization
Published 2011-05-01“…During the past several years, we have carried out a systematic study of the factors affecting the pore structure and surface chemistry of cerium oxide and of mixed oxides of cerium with various transition metal or alkaline earth metal ions.…”
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126
Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides
Published 2007-02-01“…Samples of zirconia doped with transition metal (Cr, Co, Ce) oxides, and also rhodium-promoted and Fe-containing zeolites of different structural types, were studied by NH 3 -TPD and IR spectroscopy. …”
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127
Synthesis, Characterizations and Antimicrobial Activity of Metal Complexes of 2-(2-Furanylmethylaminocarbonyl)benzoic Acid
Published 2011-01-01“…The ligand, 2-(2-furanylmethylaminocarbonyl)benzoic acid (FMBA) and it’s transition metal complexes have been synthesized and characterized by elemental analysis, spectral studies, magnetic moments and thermal studies. …”
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128
A Comparative Study of Antibacterial Activity of CuO/Ag and ZnO/Ag Nanocomposites
Published 2020-01-01“…The synergistic effects of transition metal based nanocomposites are known to possess enhanced antibacterial activities. …”
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129
Recent advances in electrochemical copper catalysis for modern organic synthesis
Published 2025-01-01“…Combining electrochemistry with transition-metal catalysis is a promising and rapidly growing methodology for effectively forming challenging C–C and C–heteroatom bonds in complex molecules in a sustainable manner. …”
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130
Synthesis, Characterization, Chelating Properties and Anti-Fungal Activity of 2-(4-Phenylpiperazinyl) Methyl-3-(8-Quinolinol-5-YL)- 4(3H)-Quinazolinone
Published 2005-01-01“…A new quinazolinone derivative namely 2-(4-phenylpiperazinyl)methyl-3-(8-quinolinol-5-yl)- 4(3h)-quinazolinone(HL) was prepared and characterized. Various transition metal (Cu2+, Co2+, Ni2+, Zn2+, Mn2+) chelates of HL were prepared and characterized by metal ligand (M:L) ratio, IR and reflectance spectral studies, magnetic moment, and antimicrobial activity.…”
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131
Metal Complexation Studies of 1-(4-Carboxy-3-hydroxy-N-methyl phenyl- amino methyl) 2-methyl perimidine
Published 2009-01-01“…The resultant compound was designed as 1-(4-caroxy-3-hydroxy-N-methyl phenylamino methyl)2-methyl perimidine. The transition metal complexes of Cu2+, Co2+, Ni2+, Mn2+ and Zn2+ have been prepared and characterized by elemental analysis, spectral studies, magnetic moment determination, molar conductivity measurement and antimicrobial activity.…”
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132
Advances in the Preparation of Fluorinated Isoquinolines: A Decade of Progress
Published 2017-01-01“…This review examines recent noncatalyzed and transition metal catalyzed synthetic approaches to the assembly of isoquinoline derivatives that are ring-fluorinated and/or result in the incorporation of fluorine-containing functional groups. …”
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133
Component regulation and high-entropy engineering for enhanced antioxidant and high-temperature mechanical properties of protective films
Published 2025-01-01“…Transition metal nitrides (TMNs) have gained widespread application in protecting structural components due to their high strength and hardness. …”
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134
A Review on Synthesis, Properties, and Environmental Application of Fe-Based Perovskite
Published 2022-01-01“…This review highlights and provides an overview of the transition metal substituent in Fe-based Perovskite and its properties and how it influences its application in wastewater treatment and catalysis. …”
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135
Synthesis of Heterogeneous Copper Catalyst Based on Amino-Functionalized Triazine Rings Supported by Silica-Gel for Oxidation of Alcohols
Published 2013-01-01“…The copper (II) content of the material was determined by atomic absorption. This novel transition metal supported on heterogeneous surface was used as an effective catalyst for oxidation of benzylic alcohols in the presence of H2O2. …”
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136
DNA Binding and Cleavage Activity of Binuclear Metal Complexes with Benzil-α-Monoxime Thiosemicarbzone
Published 2011-01-01“…Transition metal complexes of copper(II), nickel(II), cobalt(II) and iron(II) with benzil-α-monoxime thiosemicarbazone (BMOT) have been synthesized and characterized by molar conductance, magnetic moments, IR, electronic and ESR spectroscopy. …”
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137
Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes
Published 2014-01-01“…A transition metal complex, oxovanadium(IV) salen (where salen represents N,N′-bis(salicylidene)ethylenediamine) is immobilized on glassy carbon (GC) electrodes and utilized for electrocatalytic oxidation of cysteine. …”
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138
Biomimetic Approach to CO2 Reduction
Published 2018-01-01“…Besides, effective catalysts are also demanded to capture atmospheric CO2, mitigating the effects of its constantly increasing emission. Biomimetic transition metal complexes are considered ideal platforms to develop efficient and selective catalysts to be implemented in electrocatalytic and photocatalytic devices. …”
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139
Analysis of Topological Aspects for Metal-Insulator Transition Superlattice Network
Published 2022-01-01“…Also, Metal-Insulator Transition Superlattice (GST–SL) is useful in form of a thin film to utilize as two-dimensional (2D) transition metal dichalcogenides (TMDs). Moreover, we have defined the computed-based bond properties such as the degree constructed topological indices and their heat of formation for single crystal and monolayered structure of Ge-Sb-Te. …”
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140
Acid-Catalyzed, Metal- and Oxidant-Free C=C Bond Cleavage of Enaminones: One-Pot Synthesis of 3,4-Dihydroquinazolines
Published 2025-01-01“…This method operates in ethanol under transition-metal-free and oxidant-free conditions, offering a sustainable and efficient approach for the synthesis of 3,4-dihydroquinazolines with broad functional group tolerance.…”
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