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1161
Innovative Use of Wood Ash for Fluoride Removal from Water: Comprehensive Experiments and Mechanism Insight
Published 2024-12-01“…Equilibrium analysis demonstrated that WA exhibits a Langmuir maximum capacity of 157.34 mg/g, indicating a high adsorption capacity that ranks within the top 10% of reported adsorbents (34th out of 328). According to thermodynamic analysis, the adsorption process appears to be both endothermic and spontaneous at elevated temperatures. pH dependence studies showed that while the fluoride adsorption capacity of WA peaked under acidic conditions, it remained relatively stable (116.01 ± 0.8 mg/g) over a wide range of pH levels (5 to 11). …”
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1162
Stability of reinforcements (CrB2/TiB2) and lubricants (C/MoS2) in Cu matrix during the sintering process
Published 2025-01-01“…Then, microstructure and phase composition of the composites resulted from 10%CrB2–Cu, 10%TiB2–Cu, 10%MoS2–Cu, 10%C–Cu, 10%CrB2–10%C–Cu, 10%TiB2–10%C–Cu, 10%CrB2–10%MoS2–Cu and 10%TiB2–10%MoS2–Cu powder systems were investigated systematically, Subsequently, the potential decomposition and reaction behavior was discussed based thermodynamic analysis. Results show that single CrB2, TiB2 or C phase can exist stably in copper matrix, but MoS2 is prone to react with Cu to form Cu2S and Mo2S3. …”
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1163
Experimental Approach for the Evaluation of the Performance of a Satellite Module in the CanSat Form Factor for In Situ Monitoring and Remote Sensing Applications
Published 2021-01-01“…This experiment’s interest measured thermodynamic variables and the concentration of pollutants in the stratosphere to corroborate the operating ranges planned in the above experiments using on-flight conditions and estimate the TLR (technology readiness level) of future prototypes.…”
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1164
Biosynthesis and Characterization of Iron Nanoparticles for Effective Adsorption of Cr(VI)
Published 2019-01-01“…Weber–Morris model was used to investigate the effect of mass transfer on the adsorption of Cr(VI) onto FeNPs; it was observed that both the film (boundary layer) and intraparticle diffusion affected the studied adsorption process. The thermodynamic studies suggested that Cr(VI) adsorption onto FeNPs was endothermic and nonspontaneous, and the positive ΔS value indicated increased disorder at the solid-solution interface during the adsorption.…”
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1165
Using magnetic dynamics to measure the spin gap in a candidate Kitaev material
Published 2025-02-01“…This timescale aligns with the extrapolated spin gap of ~1 μeV, obtained by density matrix renormalization group (DMRG) simulations in the thermodynamic limit. The consistency demonstrates the efficacy of tr-REXS in discerning low-energy spin gaps inaccessible to conventional spectroscopic techniques.…”
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1166
Changes of Quality Characteristics before and after Embrittlement of Oreochromis niloticus×O. aureus
Published 2025-02-01“…Oreochromis niloticus×O. aureus was taken as the research object, and the difference of nutrient composition, thermodynamic property, microstructure, texture property and sensory quality between normal tilapia (NT) and crisp tilapia (CT) was analyzed to find out the effective development and utilization direction of brittle tilapia. …”
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1167
Comparative Study of the West African Continental, Coastal, and Marine Atmospheric Profiles during the Summer of 2006
Published 2012-01-01“…The vertical gradient method is applied to the profiles of some thermodynamic parameters estimated from sounding data to do a comparative study of the structure and thermal properties, moisture, and static stability of the atmospheric boundary layer of inland, coastal, and marine sites to show consistent differences related to geographic factors. …”
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1168
Extensive composable entropy for the analysis of cosmological data
Published 2025-02-01“…The Boltzmann-Gibbs-based Bekenstein-Hawking entropy SBH∝A/lP2 (A≡ area; lP≡ Planck length) systematically plays a crucial theoretical role although it has a serious drawback, namely that it violates the thermodynamic extensivity of spatially-three-dimensional systems. …”
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1169
Potential of Co(II) and Cd(II) chelates of N′-(3-fluorobenzoyl)benzo[d]thiazole-2-carbohydrazide: Structural aspects, binding interactions, biological and molecular docking studies...
Published 2025-01-01“…The complexes are non-electrolytic with octahedral geometry. The kinetic and thermodynamic parameters obtained by Coats-Redfern relations reveal that both the complexes show positive Gibbs’s free energy and negative entropy. …”
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1170
Dissolution and Solubility Product of Cd-Fluorapatite [Cd5(PO4)3F] at pH of 2–9 and 25–45°C
Published 2018-01-01“…Based on the log Ksp values obtained at an initial pH of 2 and 25°C, the Gibbs free energy of formation for Cd5(PO4)3F (ΔGf0) was calculated to be −4065.76 kJ/mol (−4064.11∼−4068.23 kJ/mol). The thermodynamic parameters for the dissolution process were computed to be 342515.78 J/K·mol, −85088.80 J/mol, −1434.91 J/K·mol, and 2339.50 J/K·mol for ΔG0, ΔH0, ΔS0, and ΔCp0, correspondingly.…”
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1171
Cost-effective adsorption of cationic dyes using ZnO nanorods supported by orange peel-derived carbon
Published 2025-02-01“…On the otherhand, the thermodynamic studies confirmed the adsorption of MB, and CV dyes onto ZnO-NR@PC composite is an endothermic and spontaneous process. …”
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1172
PGTransNet: a physics-guided transformer network for 3D ocean temperature and salinity predicting in tropical Pacific
Published 2024-11-01“…Firstly, we design a loss function that deliveries the physical relationship among temperature, salinity and density by fusing the Thermodynamic Equation. Secondly, to capture global and long-term dependencies effectively, we add the Pacific Decadal Oscillation (PDO) and North Pacific Gyre Oscillation (NPGO) in the embedding layer. …”
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1173
A deep dive into cation-modified structural, mechanical, magneto‑electronic, and thermophysical properties of MAlO3 (M = Ca, Sr, Ba, and Ra): First-principles investigation
Published 2025-03-01“…Lastly, theoretical simulations of the thermodynamic and thermoelectric properties are included in this research. …”
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1174
Selective Binding of Distamycin A Derivative to G-Quadruplex Structure [d(TGGGGT)]4
Published 2010-01-01“…Experiments show that netropsin and compound 1 are able to bind to [d(TGGGGT)]4 with good affinity and comparable thermodynamic profiles. In both cases the interactions are entropically driven processes with a small favourable enthalpic contribution. …”
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1175
Exploring advanced nanostructures and functional materials for efficient hydrogen storage: a theoretical investigation on mechanisms, adsorption process, and future directions
Published 2025-02-01“…Density Functional Theory (DFT) based computations are used to analyze binding energies, thermodynamic stability, and adsorption mechanisms. Ni-decorated C12N12 nanoclusters demonstrate enhanced storage capacities, binding up to eight H2 molecules with a favorable N-(μ-Ni)-N configuration. …”
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1176
Synthesis, Characterization, and Evaluation of the Remediation Activity of Cissus quadrangularis Zinc Oxide Nanoparticle-Activated Carbon Composite on Dieldrin in Aqueous Solution
Published 2022-01-01“…Batch adsorption experiments were performed using 20 ml of dieldrin solution at varying pH values (1–14), concentrations (5–100 ppm), temperatures (293–323 K), adsorbent dosages (0.01–0.12 g), and contact times (30–180 minutes) to determine the optimum conditions. The calculated thermodynamic parameters (ΔH°, ΔS°, and ΔG°) indicated that the adsorption was spontaneous and exothermic in nature, implying decreasing randomness of dieldrin molecules at the solid-liquid interface. …”
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1177
Evaluation of the binding affinity and antioxidant activity of phlorizin to pepsin and trypsin
Published 2024-01-01“…Fluorescence spectra showed that PHL quenches the pepsin/trypsin by static quenching. Thermodynamic parameters indicated that PHL binds to pepsin mainly through hydrogen bonds and van der Waals forces, and that of trypsin was electrostatic forces. …”
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1178
Removal of Humic Substances from Aqueous Solutions Using Carbon Quantum Dots and Activated Carbon Derived by Watermelon Rind
Published 2024-11-01“…Studies have shown that adsorption occurs in a single layer. The thermodynamic parameters show that the process is spontaneous.…”
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1179
Removal of Cd(II) and Cu(II) from Aqueous Solution by Na+-Modified Pisha Sandstone
Published 2020-01-01“…The values of the thermodynamic parameters indicated that the interactions were spontaneous endothermic reactions. …”
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1180
False Alarm Causes and Wind Field Sensitivity Analysis of a Severe Rainfall Event in the Guangdong-Hong Kong-Macao Greater Bay Area Urban Cluster
Published 2024-01-01“…The results indicate that the warm and moist airflow transported by the low-level jet stream was intercepted by the upstream MCS (mesoscale convective system) along the coastal area of western Guangdong, and inadequate conditions of negative vorticity dynamics led to insufficient moisture, thermodynamic, and dynamic conditions over the urban cluster, preventing the triggering of heavy precipitation. …”
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