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1081
Accessing ultrastable glass via a bulk transformation
Published 2025-01-01“…The resulting ultrastable glass exhibits a significantly enhanced density (improved by 2.3%), along with high thermodynamic, kinetic, and mechanical stability. Furthermore, we propose that this method of accessing ultrastable glasses is general for metallic glasses, based on the examination of the competitive relationship between the glass-to-glass transition and crystallization. …”
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1082
Estimate of the Arctic Convective Boundary Layer Height from Lidar Observations: A Case Study
Published 2012-01-01“…The results obtained are in good agreement with the PBL height estimated by the analysis of thermodynamic measurements obtained from radio sounding and with the model.…”
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1083
Holographic Renyi entropy of 2d CFT in KdV generalized ensemble
Published 2025-01-01“…We focus on the high density limit, which is equivalent to thermodynamic limit in conformal theories. In this limit holographic Renyi entropy can be computed using the so-called gluing construction. …”
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1084
Mechanistic modelling of water–oxygen bubbly flow in horizontal pipes: Deviation analysis from experimental correlations and performance comparison with CFD
Published 2025-01-01“…This was achieved by appropriately averaging the thermodynamic properties of the two involved phases. …”
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1085
CH3OH Thermal Lines Traces 6.7 GHz CH3OH Maser Variation of High-mass Protostar G353.273+0.641
Published 2025-01-01“…The CH _3 OH envelope exhibited non–local thermodynamic equilibrium (LTE) conditions during the increase phase of the flux density of the maser, then transitioning to LTE ( T ∼ 380 K) during the decay phase of the maser. …”
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1086
Comparative Studies on the Interaction of Cochinchinenin A and Loureirin B with Bovine Serum Albumin
Published 2013-01-01“…The corresponding thermodynamic parameters were also obtained and indicated that electrostatic forces play a major role in the formation of the LB-BSA complex, but probably a combined force for CA-BSA complex. …”
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1087
The Interannual Relationship between the Diabatic Heating over the South Asia and the Snow Depth over the Southern Tibetan Plateau in Late Spring to Early Summer: Roles of the Air...
Published 2023-01-01“…The acceleration of snow melting during P2 is mainly found over high elevation areas caused by the increase of local air temperature. Diagnoses of the thermodynamic equation further demonstrate that the warming over the southern TP during the two periods is mainly attributed to the meridional temperature advection and diabatic heating in situ. …”
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1088
Eco-Friendly Adsorbent from Waste of Mint: Application for the Removal of Hexavalent Chromium
Published 2021-01-01“…The experimental data fitted well to the fractional power kinetic model (0.97≤R2≤ 0.99) and Langmuir isotherm (R2 = 0.984) with a maximum adsorption capacity Qmax = 172.41 mg/g. The thermodynamic parameters for Cr(VI) sorption were also calculated, confirming that the adsorption process was spontaneous and accompanied by an exothermic adsorption (−4.83 ≤ ΔG ≤ −3.22 kJ/mol and ΔH = −28.93 kJ/mol). …”
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1089
Adsorption-Based Removal of Sb (III) from Wastewater by Graphene Oxide-Modified Zirconium-Based Metal-Organic Framework Composites
Published 2022-01-01“…The adsorption processes of Sb (III) were examined via adsorption kinetic, isotherm, and thermodynamic analyses. XRD, SEM, and FTIR analyses demonstrated the presence of a porous structure and high levels of oxygen-containing functional groups on the UiO-66-NH2 and GO@UiO-66-NH2 surfaces. …”
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1090
Spectroscopic, quantum chemical, and topological calculations of the phenylephrine molecule using density functional theory
Published 2025-01-01“…Both the global and local reactivity were studied to understand the reactivity of the PE molecule. Using the thermodynamic parameters, the thermochemical property of the title molecule was understood. …”
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1091
Bambara groundnut starch-soluble dietary fibre nanocomposite stabilised emulsions: Optimisation of emulsion stability and studies on time-dependent rheological properties
Published 2025-01-01“…Due to their inherent thermodynamic instability, emulsions require stabilisers to maintain their integrity and prevent destabilisation. …”
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1092
Alloy design for additive manufacturing: Continuously reinforced Al-Ce nanocomposites
Published 2025-02-01“…The composition Al-16Ce-1Mg has been developed as a dedicated alloy for processing by laser powder bed fusion (LPBF). Guided by thermodynamic considerations and exploiting the unique conditions during LPBF, the strongly hypereutectic alloy features nm-scale aluminum dendrites reinforced by a continuous intermetallic network. …”
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1093
Production of Nanofibers Composed of CuO for the Removal of Pb(II) from Aqueous Solutions
Published 2025-01-01“…The kinetic data proved that Pb (II) adsorption better fitted the pseudo-second-order model, while the Hill model was confirmed to best fit the equilibrium data. Thermodynamic parameters demonstrated that the lead adsorption was favorable, spontaneous, and exothermic. …”
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1094
Hydrogen Storage Materials: Promising Materials for Kazakhstan’s Hydrogen Storage Industry
Published 2024-10-01“…This review article provides an in-depth analysis of hydrogen storage materials, focusing on metal hydrides, complex hydrides, and carbon-based materials, with particular attention to their thermodynamic, structural, and kinetic properties. Additionally, the article explores the potential application of certain materials in Kazakhstan's hydrogen market, highlighting the country's rich mineral resources and existing industrial infrastructure. …”
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1095
Biosorption of Chromium and Nickel from Industrial Oil Mill Wastewater Using Groundnut Pod Waste Activated Carbon
Published 2025-02-01“…Results of the kinetic studies and thermodynamic parameters revealed that the biosorption process followed a pseudo-second-order, endothermic, and spontaneous in nature. …”
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1096
Integrated Identification and Efficient Use of Biodiversity in Mountainous Regions
Published 2025-01-01“…The purpose of the presented work is to determine the quantitative, qualitative and thermodynamic parameters of geothermal sources in these territories, as well as the spatial structure of the foci of formation of their migration routes. …”
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1097
Reductive roasting of iron-rich manganese oxide ore with elemental sulfur for selective manganese extraction
Published 2017-01-01“…The contents of manganese sulfide and sulfate in the roasted product increased with increasing sulfur addition, while they decreased distinctly at temperatures above 550°C. The thermodynamic analysis also proved that manganese dioxide is more easily reduced than iron oxide by sulfur at 300-900 K. …”
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1098
Thermal analysis of a main compression intercooling supercritical CO2 cycle cascaded with flash tank enhanced compression-absorption refrigeration cycle
Published 2025-01-01“…Besides, exergy destruction occurring throughout the components of the proposed system is analyzed. Thermodynamic optimization reveals thermal and exergy efficiencies of 54.23 % and 65.34 %, with the RMCIB subsystem’s energy efficiency improving by 15.38 % and 2nd law efficiency by 3.35 % through CCAR integration. …”
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1099
Performance of Poly(Styrene—Divinylbenzene) Magnetic Porous Microspheres Prepared by Suspension Polymerization for the Adsorption of 2, 4-Dichlorophenol and 2, 6-Dichlorophenol fro...
Published 2013-07-01“…It was found that the Langmuir isotherm model fitted the equilibrium data superior to the Freundlich model. Thermodynamic parameters were calculated by the Gibbs free energy function, confirming that adsorption process was spontaneous and endothermic. …”
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1100
Preparation of quaternary ammonium-modified silica and its adsorption of vanadium(V)
Published 2025-01-01“…The pseudo-second-order reaction kinetics and Langmuir adsorption isotherm model indicated that the process of adsorbing vanadium(Ⅴ) by SiO2@DMOA was a surface monolayer chemical adsorption process, and the intra-particle diffusion model and Boyd model demonstrated that liquid film diffusion was the main limiting rate of this adsorption process. Thermodynamic studies demonstrated the feasibility and spontaneity of vanadium(Ⅴ) adsorption by SiO2@DMOA, with ΔH0>0, ΔS0>0 and ΔG0<0. …”
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