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641
Kinetics and Mechanism of Oxidation of Glutamic Acid by N-Bromophthalimide in Aqueous Acidic Medium
Published 2011-01-01“…Also the rate increased with decrease in dielectric constant of the reaction medium. The thermodynamic parameters were computed from Arrhenius and Eyring plots. …”
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642
A model for electrochemical insertion limited by a phase transition process - eilpt
Published 2003-01-01“…Phase transformations during electrochemical insertion are taken into account, with various values for parameters such as the thermodynamic biphase equilibrium potential, the compared diffusion and phase transformation kinetics, and the electrode thickness. …”
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643
Temperature and pH Effect on the Sorption of Divalent Metal Ions by Silica Gel
Published 2003-05-01“…The values of the binding constants were used to estimate the apparent thermodynamic parameters, ΔH and ΔS, for the adsorption process. …”
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644
Effects of Zinc Binding on the Structure and Stability of Glycylglycine Dipeptide: A Computational Study
Published 2012-01-01“…The vibrational frequencies, thermodynamic and electronic properties, HOMO, LUMO, and energy gap for the most stable isomer in different solvents were calculated at the BLYP/6-311++G** level of theory.…”
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645
Electrochemical study of the electrodeposition and intercalation of sodium into graphite from sodium chloride as the first step of carbon nano-tubes formation
Published 2003-01-01“…The definition of so-called ‘thermodynamic’ or ‘material balance’ reversibility has been introduced. …”
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646
Adsorption of Phenol from Aqueous Solution by Aminated Hypercrosslinked Polymers
Published 2005-05-01“…Furthermore, these factors also influenced the thermodynamic properties. Kinetic studies demonstrated that the presence of the tertiary amino group on the polymer matrix decreased the adsorption rate and increased the apparent activation energy of the adsorption process.…”
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647
Sorption Equilibrium Studies of Toxic Nitro-Substituted Phenols on Fly Ash
Published 2004-05-01“…The adsorption of the nitrophenols studied followed first-order rate kinetics. Thermodynamic studies were also undertaken and the values of the standard free energy (ΔG 0 ), enthalpy (ΔH 0 ) and entropy (ΔS 0 ) changes calculated.…”
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648
Adsorption Properties of Low-Cost Biomaterial Derived from Prunus amygdalus L. for Dye Removal from Water
Published 2013-01-01“…The equilibrium data pointed out excellent fit to the Langmuir isotherm model with maximum monolayer adsorption capacity of 41.34 mg g−1 at 293 K. Thermodynamic analysis proved a spontaneous, favorable, and exothermic process. …”
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649
The three-dimensional N $$ \mathcal{N} $$ = 2 superfishnet theory
Published 2025-01-01“…We use techniques inspired by the integrability of bi-scalar fishnet theory and adapted to superspace to calculate the zero-mode-fixed thermodynamic free energy, the corresponding critical coupling, and the exact all-loop scaling dimensions of various operators. …”
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650
Activity of bismuth in liquid Ag-Bi-Ni alloys determined by equilibrium saturation method
Published 2015-01-01“…The experimental activity data were compared to the values calculated for two sets of assessed thermodynamic data.…”
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651
Determination of the Specific Surface Areas of Non-Porous and Macroporous Carbons
Published 2001-11-01“…This method has rigorous foundations since it utilizes the adsorption potential distribution which is a unique thermodynamic characteristic for a given adsorption system. …”
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652
Impact loading of a space nuclear powerplant
Published 2013-03-01“…A caloric model of the equation of state is proposed to describe thermodynamic properties of solid materials with the phase transitions. …”
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653
Enantioseparation of Secnidazole by High-Performance Liquid Chromatography Using Amylose-Based Stationary Phase
Published 2012-09-01“…The chromatographic parameters and the effects of column temperature on the retention time and selectivity were evaluated. Thermodynamic parameters were obtained from van't Hoff plots, and the elution order of the enantiomers was determined by circular dichorism. …”
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654
Study of Thermal Energy Production by Combustion of Lard and Diesel Mixtures
Published 2012-01-01“…The work is divided into two parts, the first of which deals with the identification of lard as fuels and characterization of diesel, as well as determining the chemical and thermodynamic properties of mixtures of both components. …”
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655
Analytical equation for the mesopore size distribution function of open cylindrical capillaries
Published 2019-07-01“…Thus a new, strictly thermodynamic method to calculate the mesopore size distribution is gained. …”
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656
An Ion Adsorption Model Related to the Change in the Standard Chemical Potential of Adsorption Reactions
Published 2011-08-01“…The establishment of the model was based on the assumption that the change in the standard chemical potential of the adsorption system should be zero if ion adsorption taking place spontaneously at a constant temperature is purely a thermodynamic process in which, driven by the electrochemical potentials, the ions move between liquid and solid phases without changing their chemical nature. …”
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657
On Boundedness of Entropy of Photon Gas in Noncommutative Spacetime
Published 2017-01-01“…As a result, the reported analogy between thermodynamics of photon gas in such NC spacetime and Bekenstein-Hawking entropy of black holes should be disregarded.…”
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658
Impact loading of a space nuclear powerplant
Published 2013-04-01“…A caloric model of the equation of state is proposed to describe thermodynamic properties of solid materials with the phase transitions. …”
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659
A Simple Way of Calculating the Change in the Gibbs' Free Energy of Ion Adsorption Reactions
Published 2009-02-01“…The functions were deduced on the basis of the thermodynamic principle that the chemical potentials of the reactants and products of a physicochemical reaction should be equal in the equilibrium state and, consequently, the change in the Gibbs' free energy between the initial and equilibrium states of the reaction should be equal to the sum of the initial molar quantity of each reactant multiplied by its change in chemical potential. …”
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660
LREE of a dressed Dp-brane with transverse motion in the partially compact spacetime
Published 2025-01-01“…Besides, we investigate the thermodynamical entropy, associated with the LREE. This demonstrates that the LREE is precisely equivalent to its thermodynamic counterpart.…”
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