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461
An Integrated Na<sub>2</sub>S−Electrocatalyst Nanostructured Cathode for Sodium–Sulfur Batteries at Room Temperature
Published 2024-12-01“…The in situ formed Na<sub>6</sub>CoS<sub>4</sub>/Co electrocatalysts, tightly integrated with Na<sub>2</sub>S, exhibit strong catalytic activity and robust physicochemical stabilization, thereby accelerating redox kinetics and mitigating the polysulfide shuttle effect. …”
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462
Reactivity in cell culture medium and in vitro anticancer activity of 3,5-di-tert-butylcatechol: link to metal-catechol interactions
Published 2025-02-01“…These studies showed that a redox equilibrium was established between dtbH2 and dtbQ, with the latter rapidly coupling the GSH in an oxidative manner. …”
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463
Edaphic factors mediate the response of nitrogen cycling and related enzymatic activities and functional genes to heavy metals: A review
Published 2025-01-01“…Environmental factors like soil organic carbon, soil texture, water content, temperature, soil pH, N fertilization, and redox status play significant roles in modulating the response of soil N cycling to HM contamination. …”
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464
Oxidative degradation of sulfamethazine by manganese oxide supported biochar activated periodate: Effect and mechanism
Published 2025-01-01“…ROS, Mn(III) and electron transfer are three crucial SMZ removal mechanisms in MBC activated PI system, and the conversion process of reactive species was deduced. The manganese redox cycles, oxygen-containing functional groups on MBC surface, and BC-O-Mn(II) complex participated in reactive species production. …”
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465
Impact of long-term cyanotoxin exposure on cattle: Biochemical, histological, and oxidative stress assessment
Published 2025-01-01“…Results: Exposed cattle exhibited significant elevations in liver enzymes and oxidative stress markers, indicating hepatic inflammation and redox imbalance. Histological analysis revealed macrovacuolar steatosis, fibrosis, and bile duct dilatation. …”
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466
Connotation, research status, and development directions of clean coal geology in China
Published 2025-01-01“…This study summarizes the compositions and distributions of beneficial and harmful components in coals and analyzes the geologic factors affecting CCT, which are primarily associated with endogenetic and exogenetic geological processes during coal formation and involve tectonics, metamorphism, volcanic eruption, magmatic intrusion, aeolian-fluvial transport and deposition, redox reactions, and groundwater. Furthermore, this study provides a comprehensive overview of the current status of research on the clean assessment, clean processing, conversion, and utilization of coal resources. …”
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467
Fluorescence Lifetime Imaging of NAD(P)H in Patients’ Lymphocytes: Evaluation of Efficacy of Immunotherapy
Published 2025-01-01“…Objective: The aim of the study was to develop a patient-derived glioma explant model enriched by autologous peripheral lymphocytes and explore FLIM of the redox-cofactor NAD(P)H in living lymphocytes to measure the responses of the model to immune checkpoint inhibitors. …”
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468
Preventive treatment with guarana powder (Paullinia cupana) mitigates acute paracetamol-induced hepatotoxicity by modulating oxidative stress
Published 2025-06-01“…This study assessed the preventive effects of guarana powder on redox status in a rat model of acute hepatotoxicity induced by a toxic dose of paracetamol. …”
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469
Dinámica metacomunitaria de la macrofauna bentónica de fondos blandos de la zona costera del Golfo de Arauco
Published 2024-12-01“…Los sitios de muestreo se asociaron a las variables potencial Redox, carbono orgánico total y tamaño medio del grano de los sedimentos. …”
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470
Kinetic Analysis of the Reduction Processes of a Cisplatin Pt(IV) Prodrug by Mesna, Thioglycolic Acid, and Thiolactic Acid
Published 2020-01-01“…Although Mesna is an FDA-approved chemotherapeutic adjuvant and an antioxidant based largely on its antioxidative properties, kinetic and mechanistic studies of its redox reactions are limited. A kinetic analysis of the reduction processes of cis-diamminetetrachloroplatinum(IV) (cis-[Pt(NH3)2Cl4], a cisplatin Pt(IV) prodrug) by thiol-containing compounds Mesna, thioglycolic acid (TGA), and DL-thiolactic acid (TLA) was carried out in this work at 25.0°C and 1.0 M ionic strength. …”
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471
Hydrogel loaded with cerium-manganese nanoparticles and nerve growth factor enhances spinal cord injury repair by modulating immune microenvironment and promoting neuronal regenera...
Published 2025-01-01“…Transmission Electron Microscopy, Selected-Area Electron Diffraction, X-ray Diffraction and X-ray Photoelectron Spectroscopy confirmed their crystalline structure, mixed-valence states, and redox properties. Size uniformity, biocompatibility, and catalytic activity were assessed via hydrodynamic diameter, zeta potential, and elemental analysis. …”
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472
Metal complexes in cells: from design of catalytic antioxidants to imaging metal ions and designing metal-based probes in X-ray fluorescence and IR-imaging, a multidisciplinary col...
Published 2024-03-01“…Starting from the description of the main features of an antioxidant cell-protecting metalloenzyme, the superoxide dismutase (SOD), we will delineate the main parameters to be controlled to design low-molecular weight (LMW) metal complexes meant to mimic its activity: choice of the metal cation, tuning of the redox potential, and modulation of the charge. The effect of the hydration level and inertness with regard to metal ion release have also been explored. …”
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473
The promotion effect of FeS2 on Sb2S3 bioleaching and Sb speciation transformation
Published 2025-01-01“…The electrochemical results revealed that after FeS2 was mixed, a FeS2-Sb2S3 galvanic cell formed, which promoted the electron transfer efficiency and redox reaction of Sb2S3. The DFT results show that between the Sb2S3 (0 1 0) and FeS2 (1 0 0) surfaces, S-Fe, S-S, S-Sb, and Sb-Fe bonds are formed, and the direction of electron transfer is from Sb2S3 to FeS2; the work functions for Sb2S3 after addition of FeS2 decrease, implying that faster electron transfer occurs; Fe(III)-6H2O derived from FeS2 adsorbs on the surface more easily than does glucose, which is the major component of the extracellular polymeric substances in bacteria, indicating that during the bioleaching process, Fe(III)-6H2O plays an important role; after mixing, both Fe(III)-6H2O and glucose adsorb on the Sb2S3 (0 1 0) surface more easily, with stronger bonds and larger adsorption energies, which are in good agreement with the experimental results.…”
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474
Impaired peroxisomal beta-oxidation in microglia triggers oxidative stress and impacts neurons and oligodendrocytes
Published 2025-01-01“…Transcriptomic analysis of the mutant microglial cells revealed numerous differentially expressed genes, particularly in redox-related pathways following LPS exposure. These changes are consistent with the increased production of reactive oxygen species (ROS) and nitric oxide (NO). …”
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475
Mechanism Analysis of Organic Matter Enrichment of Upper Ordovician-Lower Silurian Shale in the Upper Yangtze Area: Taking Jiaoye-1 Well in the Jiaoshiba Block as an Example
Published 2019-01-01“…The shale of the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in the Yangtze area is the research object. Choosing redox indicator and biological productivity indicator, the study explores the enrichment mechanism of sedimentary organic matter from two aspects, sealing of water and volcanic activity. …”
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476
Tumor microenvironment-responsive hyperbranched polymers for controlled drug delivery
Published 2024-12-01“…Here, based on different types of tumor microenvironment stimulation signals such as pH, redox, temperature, etc., we systematically review the preparation and response mechanism of HBPs, summarize the latest advances in drug delivery applications, and analyze the challenges and future research directions for such nanomaterials in biomedical clinical applications.…”
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477
MnS/MnO heterostructures with dual ion defects for high-performance aqueous magnesium ion capacitors
Published 2025-01-01“…Moreover, DID-MnS/MnO enhances conductivity, improves the kinetics of surface redox reactions, and increases the diffusion rate of Mg2+. …”
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478
Surface Modifications of Layered Perovskite Oxysulfide Photocatalyst Y2Ti2O5S2 to Enhance Visible‐Light‐Driven Water Splitting
Published 2025-01-01“…Abstract Increasing the efficiency of visible‐light‐driven water splitting systems will require improvements in the charge separation characteristics and redox reaction kinetics associated with narrow‐bandgap photocatalysts. …”
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479
Effect of the season on blood changes of oxidative stress index (OSi) in the Italian Mediterranean Buffalo (Bubalis bubalis
Published 2023-11-01“… The oxidative stress index (OSi) has recently been used as a valid tool for providing an in-depth picture of redox status and oxidative stress. Previous studies in cattle showed that high temperatures increase the production of reactive oxygen species (ROS), causing an imbalance between ROS and the ability of antioxidant systems to detoxify and remove the reactive intermediates. …”
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480
Auxin signaling related to H+-ATPase synthesis and antioxidant enzyme activities regulates fluoranthene uptake by ryegrass roots
Published 2025-02-01“…Moreover, the promoted expression of redox-related genes (POD1, SOD1 and SOD2) further reduced Flu uptake. …”
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