Generation of Phthalimido-Nitrene and its Reactions by L. Hoesch, A.S. Dreiding

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Comparative Nitrene-Transfer Chemistry to Olefins Mediated by First-Row Transition Metal Catalysts Supported by a Pyridinophane Macrocycle with N4 Ligation by Himanshu Bhatia, Lillian P. Adams, Ingrid Cordsiemon, Suraj Kumar Sahoo, Amitava Choudhury, Thomas R. Cundari, Pericles Stavropoulos

Subjects: “…nitrene transfer…”
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Dioxazolones as electrophilic amide sources in copper-catalyzed and -mediated transformations by Seungmin Lee, Minsuk Kim, Hyewon Han, Jongwoo Son

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Flash Pyrolysis – Synthetic and Mechanistic Aspects by Curt Wentrup

“…Cyanocyclopentadienes, -indenes, and -pyrroles are produced by pyrolysis of the appropriate triazoloarenes or isatins, or as the end products of carbene-nitrene rearrangements. Fulvenallene is formed from benzocyclopropene, phthalide, phenyldiazomethane, 7-norbornadienyl acetate, and other precursors. …”
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Competitive Heavy‐Atom Tunneling Reactions Controlled Through Electronic Effects by José P. L. Roque, Cláudio M. Nunes, Fumito Saito, Bastian Bernhardt, Rui Fausto, Peter R. Schreiner

“…As the electron‐donating strength of the substituent increases, the QMT ring‐opening to nitrene starts to compete with the QMT ring‐expansion to ketenimine, becoming the dominant process for the strongest electron‐donating substituent [N(CH2)4]. …”
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Screening and dissecting electroorganic synthesis by mass spectrometry decoupling of electrode and homogeneous processes by Xuemeng Zhang, Yiteng Zhang, Mengfan Li, Qibo Yan, Weifeng Lu, Jun-Jie Zhu, Xu Cheng, Qianhao Min

“…The utility of this platform is highlighted by 1) discovery and verification of quasi-electrocatalytic pathways in electrooxidative C-H/N-H cross-coupling, 2) kinetic measurements of TEMPOH-mediated dehydrogenation of N-heterocycles, and 3) mapping the landscape of intermediates (alkene radical cation and nitrene) in electrochemical aziridination.…”
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