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A Methodical Review on Carbon-Based Nanomaterials in Energy-Related Applications
Published 2022-01-01“…Carbon nanomaterials are endowed with novel and magnificent optical, electrical, chemical, mechanical, and thermal properties, with a promising prospect in different advanced applications such as electronics, batteries, capacitors, wastewater treatment, membranes, heterogeneous catalysis, and medical sciences. However, macroscopic synthesis of carbon materials for industrial use has been a great challenge. …”
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SYNTHESIS OF THE ZSM-5 ZEOLITE WITH MIXTURES BINARY OF TETRAETHYLAMMONIUM HYDROXIDE AND AMINES AS ORGANIC STRUCTURE DIRECTING AGENTS
Published 2020-09-01“… Among the microporous materials used in heterogeneous catalysis, zeolites have become promising due to the relevant physicochemical and catalytic properties. …”
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Assessment of the Oxidative Desulfurization of Middle Distillate Surrogate Fuels with Spectroscopic Techniques
Published 2020-01-01“…The goal of this study was the implementation of a simple and economical oxidative and extractive system for the desulfurization of surrogate mixtures with an intermediate sulfur concentration 1% w/w, at the mild temperature of 70°C, and without the use of supplementary and assisting methods such as heterogeneous catalysis or ultrasound irradiation. The sulfur content was estimated using X-ray fluorescence. …”
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Diffusion-programmed catalysis in nanoporous material
Published 2025-02-01“…Abstract In the realm of heterogeneous catalysis, the diffusion of reactants into catalytically active sites stands as a pivotal determinant influencing both turnover frequency and geometric selectivity in product formation. …”
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Recent catalytic advances in the production of adipic acid and its esters from bio-based C6 molecules and carbon dioxide
Published 2025-12-01“…Here, we review the eco-friendly valorization of renewable bio-based C6 molecules, such as 5-hydroxymethylfurfural derivatives (e.g. 2,5-furandicarboxylic acid, 2,5-tetrahydrofuran dicarboxylic acid, and 1,6-hexanediol), sugar acid derivatives (i.e. d-glucaric acid, d-glucarate-6,3-lactone esters, glucarodilactone, mucic acid, and muconic acid), and CO2 into AA and its esters through a wide assortment of homogeneous and heterogeneous catalysis. The aspects of catalyst evaluation, operating conditions, and reaction mechanisms are comprehensively discussed. …”
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Important role of H2 spillover in asymmetric hydrogenation of quinolines in hybrid systems
Published 2025-02-01“…The hydrogen spillover makes it possible for heterogeneous catalysts and homogeneous organometallic complexes to cooperate, breaking the boundary between homogeneous and heterogeneous catalysis.…”
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Frustrated Lewis pairs on nanoparticles for colloidal catalysis: dream or reality?
Published 2024-12-01“…These surface FLPs are emerging as promising materials in heterogeneous catalysis, but they remain underdeveloped in the field of transition metal nanoparticles.Here, we propose and illustrate the design of metal nanoparticles in colloidal suspension as Lewis acid partners of a “NanoFLP”, that is, a frustrated Lewis pair in which one partner is the nanoparticle surface and the other is a molecular Lewis base. …”
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Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure
Published 2013-01-01“…The structural characteristics of MIL-100(Fe) make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C) under static conditions. …”
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Steering acidic oxygen reduction selectivity of single-atom catalysts through the second sphere effect
Published 2024-12-01“…This work provides an appealed approach for enzyme-like catalyst design, bridging the gap between enzymatic and heterogeneous catalysis.…”
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Evaluation of diesel engine performance and emissions using biodiesel from waste oils synthesized with Fe3O4-SiO2 heterogeneous nano catalyst
Published 2025-01-01“…Conclusion: The study introduces significant advancements in biodiesel production technology through combining heterogeneous catalysis and ultrasound processing, optimizing production parameters for efficiency and sustainability while demonstrating improved environmental performance in diesel engines.…”
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