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501
Turning the Surface Electronic Effect Over Core‐Shell CoS2─FexCo1‐xS2 Nanooctahedra Toward Electrochemical Water Splitting in the Alkaline Medium
Published 2025-01-01“…By various X‐ray spectroscopies as well as electron microscopy, the results showed that the shells of CoS2─FexCo1‐xS2 nanooctahedra formed the {111} surfaces of Fe0.9Co1.0S2 and Fe0.25Co0.75S2 with and without the promotion by OH− anions during the syntheses. Catalyzed by the CoS2, Fe0.25Co0.75S2, and Fe0.9Co1.0S2 {111} surfaces, the results of alkaline OER and HER indicated the Fe0.9Co1.0S2 the most superior activities by virtue of the optimized Fe─Co electronic effect. …”
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502
Tetrazenyl-, Imido-, and Azidoaluminate Derivatives of a Sterically Demanding Bis-Silazide Ligand
Published 2025-01-01“…Attempts to synthesise the azide [{SiN<sup>Dipp</sup>}AlN<sub>3</sub>] by reaction of [{SiN<sup>Dipp</sup>}AlI] with an excess of KN<sub>3</sub> resulted in exclusive formation of the bis(azido)aluminate [{SiN<sup>Dipp</sup>}Al(N<sub>3</sub>)<sub>2</sub>K], which crystallises as an infinite 1-dimensional polymer propagated by μ-(1,3)-N<sub>3</sub> bridging interactions between the potassium cations and azide anions. Although the THF-adducted azide [{SiN<sup>Dipp</sup>}AlN<sub>3</sub>(THF)] may be synthesised and characterised by more stringent control of the reaction stoichiometry, the synthetic viability of this route remains compromised by competitive generation of [{SiN<sup>Dipp</sup>}Al(N<sub>3</sub>)<sub>2</sub>K].…”
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503
Green synthesis of nano-copper oxide using Sargassum sp. functionalized in cellulose acetate membrane for dye adsorption
Published 2024-10-01“…Additionally, the adsorption of cationic dye in cellulose acetate composite is enhanced, while the adsorption of anionic dye is diminished.…”
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504
Deciphering the role of flutamide, fluorouracil, and furomollugin based ionic liquids in potent anticancer agents: Quantum chemical, medicinal, molecular docking and MD simulation...
Published 2025-01-01“…In this work, we explored the electronic interionic interactions, stability, and reactivity of FDA approved drug-based cations flutamide ([FT1]+, [FT2]+), fluorouracil ([FU1]+), and furomollugin ([FM1]+, [FM2]+), paired with amino acid [NH]−, nitrate [NO3]−, and triflate [CF3]− anions, in gas and solvent phases (benzene and water). …”
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505
Eu-Substituents-Induced Modifications in the Thermoelectric Properties of the Zintl Phase Ba<sub>1-<i>x</i></sub>Eu<i><sub>x</sub></i>Zn<sub>2</sub>Sb<sub>2</sub> System
Published 2025-01-01“…The radius ratio criterion, based on the cationic and anionic elements (i.e., <i>r</i><sub>+</sub>/<i>r</i><sub>−</sub>), was successfully verified in the title system, as in our previous reports, where <i>r</i><sub>+</sub>/<i>r</i><sub>−</sub> > 1 for the BaCu<sub>2</sub>S<sub>2</sub>-type structure. …”
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