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    «Green-Ligand» in Metallodrugs Design—Cu(II) Complex with Phytic Acid: Synthetic Approach, EPR-Spectroscopy, and Antimycobacterial Activity by Kseniya A. Koshenskova, Natalia V. Makarenko, Fedor M. Dolgushin, Dmitriy S. Yambulatov, Olga B. Bekker, Matvey V. Fedin, Sergei A. Dementev, Olesya A. Krumkacheva, Igor L. Eremenko, Irina A. Lutsenko

    Published 2025-01-01
    “…The interaction of sodium phytate hydrate C<sub>6</sub>H<sub>18</sub>O<sub>24</sub>P<sub>6</sub>·xNa·yH<sub>2</sub>O (phytNa) with Cu(OAc)<sub>2</sub>·H<sub>2</sub>O and 1,10-phenanthroline (phen) led to the anionic tetranuclear complex [Cu<sub>4</sub>(H<sub>2</sub>O)<sub>4</sub>(phen)<sub>4</sub>(phyt)]·2Na<sup>+</sup>·2NH<sub>4</sub><sup>+</sup>·32H<sub>2</sub>O (<b>1</b>), the structure of the latter was determined by X-ray diffraction analysis. …”
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