Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative

p-tert-butylcalix[4]arene was synthesized with the condesation reaction of p-tert-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-...

Full description

Saved in:
Bibliographic Details
Main Authors: E. ERDEM, M. YENIÇERI, Ç. AYDIN, R. MAMMADOV, S. SÖYLEYICI
Format: Article
Language:English
Published: izzet kara 2014-07-01
Series:International Journal of Secondary Metabolite
Subjects:
Online Access:https://dergipark.org.tr/tr/pub/ijsm/issue/22526/240745?publisher=ijate
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849468227768287232
author E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
author_facet E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
author_sort E. ERDEM
collection DOAJ
description p-tert-butylcalix[4]arene was synthesized with the condesation reaction of p-tert-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) was synthesized with appropriate pyrrole and aldehyde compounds and then was bonded p-tert-butylcalix[4]arene derivative via lower rim hydroxyl groups.The antioxidant activity of the calix[4]arene-BODIPY compound were determined using β-karotene-linoleic acid system. Moreover, the free radical scavenging activity values were tested with DPPH free radical. The compound showed strong antioxidant activity.Total antioxidant activity of the compound was determined using β–carotenelinoleic acid model system and was found the antioxidant activity of 72,50%. The free radical scavenging activities were determined as 75.19%. Results show that, calix[4]arene-BODIPY compound has the antioxidant activity.
format Article
id doaj-art-ffce54a50b9b49f289b2a24d35c64d3a
institution Kabale University
issn 2148-6905
language English
publishDate 2014-07-01
publisher izzet kara
record_format Article
series International Journal of Secondary Metabolite
spelling doaj-art-ffce54a50b9b49f289b2a24d35c64d3a2025-08-20T03:25:54Zengizzet karaInternational Journal of Secondary Metabolite2148-69052014-07-0111200618Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy DerivativeE. ERDEM0M. YENIÇERI1Ç. AYDIN2R. MAMMADOV3S. SÖYLEYICI????p-tert-butylcalix[4]arene was synthesized with the condesation reaction of p-tert-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) was synthesized with appropriate pyrrole and aldehyde compounds and then was bonded p-tert-butylcalix[4]arene derivative via lower rim hydroxyl groups.The antioxidant activity of the calix[4]arene-BODIPY compound were determined using β-karotene-linoleic acid system. Moreover, the free radical scavenging activity values were tested with DPPH free radical. The compound showed strong antioxidant activity.Total antioxidant activity of the compound was determined using β–carotenelinoleic acid model system and was found the antioxidant activity of 72,50%. The free radical scavenging activities were determined as 75.19%. Results show that, calix[4]arene-BODIPY compound has the antioxidant activity.https://dergipark.org.tr/tr/pub/ijsm/issue/22526/240745?publisher=ijateantioxidant activity dpph calix[4]arene bodipy calix[4]arene-bodipy derivative
spellingShingle E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
International Journal of Secondary Metabolite
antioxidant activity
dpph
calix[4]arene
bodipy
calix[4]arene-bodipy derivative
title Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_full Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_fullStr Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_full_unstemmed Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_short Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_sort antioxidant and dpph 1 1 diphenyl 2 picrylhydrazyl free radical scavenging activities of new the calix 4 arene bodipy derivative
topic antioxidant activity
dpph
calix[4]arene
bodipy
calix[4]arene-bodipy derivative
url https://dergipark.org.tr/tr/pub/ijsm/issue/22526/240745?publisher=ijate
work_keys_str_mv AT eerdem antioxidantanddpph11diphenyl2picrylhydrazylfreeradicalscavengingactivitiesofnewthecalix4arenebodipyderivative
AT myeniceri antioxidantanddpph11diphenyl2picrylhydrazylfreeradicalscavengingactivitiesofnewthecalix4arenebodipyderivative
AT caydin antioxidantanddpph11diphenyl2picrylhydrazylfreeradicalscavengingactivitiesofnewthecalix4arenebodipyderivative
AT rmammadov antioxidantanddpph11diphenyl2picrylhydrazylfreeradicalscavengingactivitiesofnewthecalix4arenebodipyderivative
AT ssoyleyici antioxidantanddpph11diphenyl2picrylhydrazylfreeradicalscavengingactivitiesofnewthecalix4arenebodipyderivative