Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices

Copolymers based on fluorene-thiophene units have presented promising efficiencies in photovoltaic devices applications. They present good transport properties mainly after thermal treatment of the polymer films. Here, we investigate the properties of bilayer devices formed by the heterojunction of...

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Main Authors: Natasha A. D. Yamamoto, Andreia G. Macedo, Lucimara S. Roman
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2012/513457
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author Natasha A. D. Yamamoto
Andreia G. Macedo
Lucimara S. Roman
author_facet Natasha A. D. Yamamoto
Andreia G. Macedo
Lucimara S. Roman
author_sort Natasha A. D. Yamamoto
collection DOAJ
description Copolymers based on fluorene-thiophene units have presented promising efficiencies in photovoltaic devices applications. They present good transport properties mainly after thermal treatment of the polymer films. Here, we investigate the properties of bilayer devices formed by the heterojunction of the polymer F8T2 with variable thickness and the fullerene. The series resistance of the equivalent circuit associated with the device increases as the polymer film gets thicker. The current-voltage characteristics of the bilayer devices follow the Mott-Gurney law of SCLC. For the best performing device we measured 2.1% of power conversion efficiency.
format Article
id doaj-art-ff8b4aedeb33440e87ee830cf0d7a45c
institution Kabale University
issn 1687-9503
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language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-ff8b4aedeb33440e87ee830cf0d7a45c2025-02-03T05:44:04ZengWileyJournal of Nanotechnology1687-95031687-95112012-01-01201210.1155/2012/513457513457Thickness Effect on F8T2/C60 Bilayer Photovoltaic DevicesNatasha A. D. Yamamoto0Andreia G. Macedo1Lucimara S. Roman2Grupo de Dispositivos Nanoestruturados, Departamento de Física, Universidade Federal do Paraná, 8153-990 Curitiba, PR, BrazilGrupo de Dispositivos Nanoestruturados, Departamento de Física, Universidade Federal do Paraná, 8153-990 Curitiba, PR, BrazilGrupo de Dispositivos Nanoestruturados, Departamento de Física, Universidade Federal do Paraná, 8153-990 Curitiba, PR, BrazilCopolymers based on fluorene-thiophene units have presented promising efficiencies in photovoltaic devices applications. They present good transport properties mainly after thermal treatment of the polymer films. Here, we investigate the properties of bilayer devices formed by the heterojunction of the polymer F8T2 with variable thickness and the fullerene. The series resistance of the equivalent circuit associated with the device increases as the polymer film gets thicker. The current-voltage characteristics of the bilayer devices follow the Mott-Gurney law of SCLC. For the best performing device we measured 2.1% of power conversion efficiency.http://dx.doi.org/10.1155/2012/513457
spellingShingle Natasha A. D. Yamamoto
Andreia G. Macedo
Lucimara S. Roman
Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices
Journal of Nanotechnology
title Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices
title_full Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices
title_fullStr Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices
title_full_unstemmed Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices
title_short Thickness Effect on F8T2/C60 Bilayer Photovoltaic Devices
title_sort thickness effect on f8t2 c60 bilayer photovoltaic devices
url http://dx.doi.org/10.1155/2012/513457
work_keys_str_mv AT natashaadyamamoto thicknesseffectonf8t2c60bilayerphotovoltaicdevices
AT andreiagmacedo thicknesseffectonf8t2c60bilayerphotovoltaicdevices
AT lucimarasroman thicknesseffectonf8t2c60bilayerphotovoltaicdevices