Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel

From the Reaction between cellulose and chloro sulfonic acid was prepared sulfuric acid cellulose composition as a new solid acid. The solid acid supported on silica gel and then as an effective catalyst in Friedel-Crafts alkylation of alcohols and aromatic compounds was used. The reaction progress...

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Main Authors: A. R. Kiasat, M. Karimi-Cheshmeali, R. Soleymani, H. Rajabzadeh
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/610579
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author A. R. Kiasat
M. Karimi-Cheshmeali
R. Soleymani
H. Rajabzadeh
author_facet A. R. Kiasat
M. Karimi-Cheshmeali
R. Soleymani
H. Rajabzadeh
author_sort A. R. Kiasat
collection DOAJ
description From the Reaction between cellulose and chloro sulfonic acid was prepared sulfuric acid cellulose composition as a new solid acid. The solid acid supported on silica gel and then as an effective catalyst in Friedel-Crafts alkylation of alcohols and aromatic compounds was used. The reaction progress was controlled using thin layer chromatography and the reaction products were analyzed using IR spectroscopy devise. The results show this new catalyst is effective in the friedel crafts alkylation and C-C bond formation was done in short time with very good yields.
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institution Kabale University
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language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series E-Journal of Chemistry
spelling doaj-art-ff15911d3d3e4903ab613f94ef71d3942025-02-03T01:11:17ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01941875188410.1155/2012/610579Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica GelA. R. Kiasat0M. Karimi-Cheshmeali1R. Soleymani2H. Rajabzadeh3Department of Chemistry, Shahid Chamran University, Ahvaz, IranDepartment of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, IranYoung Researchers Club, Shahre Rey Branch, Islamic Azad University, Tehran, IranDepartment of Chemistry, Dezful Branch, Islamic Azad University, Dezful, IranFrom the Reaction between cellulose and chloro sulfonic acid was prepared sulfuric acid cellulose composition as a new solid acid. The solid acid supported on silica gel and then as an effective catalyst in Friedel-Crafts alkylation of alcohols and aromatic compounds was used. The reaction progress was controlled using thin layer chromatography and the reaction products were analyzed using IR spectroscopy devise. The results show this new catalyst is effective in the friedel crafts alkylation and C-C bond formation was done in short time with very good yields.http://dx.doi.org/10.1155/2012/610579
spellingShingle A. R. Kiasat
M. Karimi-Cheshmeali
R. Soleymani
H. Rajabzadeh
Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel
E-Journal of Chemistry
title Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel
title_full Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel
title_fullStr Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel
title_full_unstemmed Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel
title_short Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel
title_sort investigation of friedel crafts alkylation in the presence of supported sulfonic acid on silica gel
url http://dx.doi.org/10.1155/2012/610579
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AT mkarimicheshmeali investigationoffriedelcraftsalkylationinthepresenceofsupportedsulfonicacidonsilicagel
AT rsoleymani investigationoffriedelcraftsalkylationinthepresenceofsupportedsulfonicacidonsilicagel
AT hrajabzadeh investigationoffriedelcraftsalkylationinthepresenceofsupportedsulfonicacidonsilicagel