Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers

Single-crystal nanowhiskers (NWs) composed of fullerene C70 molecules were synthesized by the liquid-liquid interfacial precipitation method that used m-xylene as a saturated solution of C70 molecules. Bending behavior of the individual NWs was observed by in situ transmission electron microscopy eq...

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Main Authors: Tokushi Kizuka, Kun'ichi Miyazawa, Takayuki Tokumine
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2012/583817
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author Tokushi Kizuka
Kun'ichi Miyazawa
Takayuki Tokumine
author_facet Tokushi Kizuka
Kun'ichi Miyazawa
Takayuki Tokumine
author_sort Tokushi Kizuka
collection DOAJ
description Single-crystal nanowhiskers (NWs) composed of fullerene C70 molecules were synthesized by the liquid-liquid interfacial precipitation method that used m-xylene as a saturated solution of C70 molecules. Bending behavior of the individual NWs was observed by in situ transmission electron microscopy equipped with nanonewton force measurements using an optical deflection method. The Young’s modulus of the NWs was estimated to be 0.3–1.9 GPa, which was 2–7% of the moduli of fullerene NWs with similar diameters synthesized using other solvents, that is, toluene and pyridine. The influence of the solvent used in the precipitation method on Young’s modulus is discussed.
format Article
id doaj-art-febe968e5184408e99b64b01178df6a6
institution Kabale University
issn 1687-9503
1687-9511
language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-febe968e5184408e99b64b01178df6a62025-02-03T06:44:48ZengWileyJournal of Nanotechnology1687-95031687-95112012-01-01201210.1155/2012/583817583817Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 NanowhiskersTokushi Kizuka0Kun'ichi Miyazawa1Takayuki Tokumine2Institute of Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8753, JapanFullerene Engineering Group, Materials Processing Unit, National Institute for Materials Science, Namiki, Tsukuba, Ibaraki 305-0044, JapanInstitute of Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8753, JapanSingle-crystal nanowhiskers (NWs) composed of fullerene C70 molecules were synthesized by the liquid-liquid interfacial precipitation method that used m-xylene as a saturated solution of C70 molecules. Bending behavior of the individual NWs was observed by in situ transmission electron microscopy equipped with nanonewton force measurements using an optical deflection method. The Young’s modulus of the NWs was estimated to be 0.3–1.9 GPa, which was 2–7% of the moduli of fullerene NWs with similar diameters synthesized using other solvents, that is, toluene and pyridine. The influence of the solvent used in the precipitation method on Young’s modulus is discussed.http://dx.doi.org/10.1155/2012/583817
spellingShingle Tokushi Kizuka
Kun'ichi Miyazawa
Takayuki Tokumine
Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers
Journal of Nanotechnology
title Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers
title_full Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers
title_fullStr Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers
title_full_unstemmed Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers
title_short Solvation-Assisted Young’s Modulus Control of Single-Crystal Fullerene C𝟕𝟎 Nanowhiskers
title_sort solvation assisted young s modulus control of single crystal fullerene c𝟕𝟎 nanowhiskers
url http://dx.doi.org/10.1155/2012/583817
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AT takayukitokumine solvationassistedyoungsmoduluscontrolofsinglecrystalfullerenec70nanowhiskers