Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
Yb/Er codoped Gd(OH)3 was synthesized firstly via a simple hydrothermal treatment of the corresponding nitrate in the presence of alkali by tuning the pH values. The Gd2O3:Yb/Er nanocrystals were obtained via sintering the corresponding hydroxides precursors. The as-prepared samples were characteriz...
Saved in:
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Wiley
2013-01-01
|
Series: | Advances in Condensed Matter Physics |
Online Access: | http://dx.doi.org/10.1155/2013/509374 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
_version_ | 1832556652623036416 |
---|---|
author | Zhigao Yi Boyun Wen Chao Qian Haibo Wang Ling Rao Hongrong Liu Songjun Zeng |
author_facet | Zhigao Yi Boyun Wen Chao Qian Haibo Wang Ling Rao Hongrong Liu Songjun Zeng |
author_sort | Zhigao Yi |
collection | DOAJ |
description | Yb/Er codoped Gd(OH)3 was synthesized firstly via a simple hydrothermal treatment of the corresponding nitrate in the presence of alkali by tuning the pH values. The Gd2O3:Yb/Er nanocrystals were obtained via sintering the corresponding hydroxides precursors. The as-prepared samples were characterized by the typical X-ray diffraction, energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), high-resolution TEM, and spectrophotometer. The results revealed that two shapes of the as-prepared Gd2O3:Yb/Er nanocrystals can be readily tuned from lemon-like particle to rod-like structure via tuning pH values from 7 to 14. Moreover, compared with the samples prepared at pH 7, the Gd2O3:Yb/Er nanocrystals prepared at pH 14 exhibit enhanced red upconversion emission and higher upconversion luminescence intensity under the excitation of 980 nm laser. |
format | Article |
id | doaj-art-febe604557e8444f8b6d67d9c10f0af1 |
institution | Kabale University |
issn | 1687-8108 1687-8124 |
language | English |
publishDate | 2013-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Condensed Matter Physics |
spelling | doaj-art-febe604557e8444f8b6d67d9c10f0af12025-02-03T05:44:52ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242013-01-01201310.1155/2013/509374509374Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er NanocrystalsZhigao Yi0Boyun Wen1Chao Qian2Haibo Wang3Ling Rao4Hongrong Liu5Songjun Zeng6College of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaYb/Er codoped Gd(OH)3 was synthesized firstly via a simple hydrothermal treatment of the corresponding nitrate in the presence of alkali by tuning the pH values. The Gd2O3:Yb/Er nanocrystals were obtained via sintering the corresponding hydroxides precursors. The as-prepared samples were characterized by the typical X-ray diffraction, energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), high-resolution TEM, and spectrophotometer. The results revealed that two shapes of the as-prepared Gd2O3:Yb/Er nanocrystals can be readily tuned from lemon-like particle to rod-like structure via tuning pH values from 7 to 14. Moreover, compared with the samples prepared at pH 7, the Gd2O3:Yb/Er nanocrystals prepared at pH 14 exhibit enhanced red upconversion emission and higher upconversion luminescence intensity under the excitation of 980 nm laser.http://dx.doi.org/10.1155/2013/509374 |
spellingShingle | Zhigao Yi Boyun Wen Chao Qian Haibo Wang Ling Rao Hongrong Liu Songjun Zeng Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals Advances in Condensed Matter Physics |
title | Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals |
title_full | Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals |
title_fullStr | Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals |
title_full_unstemmed | Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals |
title_short | Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals |
title_sort | intense red upconversion emission and shape controlled synthesis of gd2o3 yb er nanocrystals |
url | http://dx.doi.org/10.1155/2013/509374 |
work_keys_str_mv | AT zhigaoyi intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals AT boyunwen intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals AT chaoqian intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals AT haibowang intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals AT lingrao intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals AT hongrongliu intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals AT songjunzeng intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals |