Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals

Yb/Er codoped Gd(OH)3 was synthesized firstly via a simple hydrothermal treatment of the corresponding nitrate in the presence of alkali by tuning the pH values. The Gd2O3:Yb/Er nanocrystals were obtained via sintering the corresponding hydroxides precursors. The as-prepared samples were characteriz...

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Main Authors: Zhigao Yi, Boyun Wen, Chao Qian, Haibo Wang, Ling Rao, Hongrong Liu, Songjun Zeng
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2013/509374
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author Zhigao Yi
Boyun Wen
Chao Qian
Haibo Wang
Ling Rao
Hongrong Liu
Songjun Zeng
author_facet Zhigao Yi
Boyun Wen
Chao Qian
Haibo Wang
Ling Rao
Hongrong Liu
Songjun Zeng
author_sort Zhigao Yi
collection DOAJ
description Yb/Er codoped Gd(OH)3 was synthesized firstly via a simple hydrothermal treatment of the corresponding nitrate in the presence of alkali by tuning the pH values. The Gd2O3:Yb/Er nanocrystals were obtained via sintering the corresponding hydroxides precursors. The as-prepared samples were characterized by the typical X-ray diffraction, energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), high-resolution TEM, and spectrophotometer. The results revealed that two shapes of the as-prepared Gd2O3:Yb/Er nanocrystals can be readily tuned from lemon-like particle to rod-like structure via tuning pH values from 7 to 14. Moreover, compared with the samples prepared at pH 7, the Gd2O3:Yb/Er nanocrystals prepared at pH 14 exhibit enhanced red upconversion emission and higher upconversion luminescence intensity under the excitation of 980 nm laser.
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institution Kabale University
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publishDate 2013-01-01
publisher Wiley
record_format Article
series Advances in Condensed Matter Physics
spelling doaj-art-febe604557e8444f8b6d67d9c10f0af12025-02-03T05:44:52ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242013-01-01201310.1155/2013/509374509374Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er NanocrystalsZhigao Yi0Boyun Wen1Chao Qian2Haibo Wang3Ling Rao4Hongrong Liu5Songjun Zeng6College of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaCollege of Physics and Information Science and Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of the Ministry of Education, Hunan Normal University, Changsha, Hunan 410081, ChinaYb/Er codoped Gd(OH)3 was synthesized firstly via a simple hydrothermal treatment of the corresponding nitrate in the presence of alkali by tuning the pH values. The Gd2O3:Yb/Er nanocrystals were obtained via sintering the corresponding hydroxides precursors. The as-prepared samples were characterized by the typical X-ray diffraction, energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), high-resolution TEM, and spectrophotometer. The results revealed that two shapes of the as-prepared Gd2O3:Yb/Er nanocrystals can be readily tuned from lemon-like particle to rod-like structure via tuning pH values from 7 to 14. Moreover, compared with the samples prepared at pH 7, the Gd2O3:Yb/Er nanocrystals prepared at pH 14 exhibit enhanced red upconversion emission and higher upconversion luminescence intensity under the excitation of 980 nm laser.http://dx.doi.org/10.1155/2013/509374
spellingShingle Zhigao Yi
Boyun Wen
Chao Qian
Haibo Wang
Ling Rao
Hongrong Liu
Songjun Zeng
Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
Advances in Condensed Matter Physics
title Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
title_full Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
title_fullStr Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
title_full_unstemmed Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
title_short Intense Red Upconversion Emission and Shape Controlled Synthesis of Gd2O3:Yb/Er Nanocrystals
title_sort intense red upconversion emission and shape controlled synthesis of gd2o3 yb er nanocrystals
url http://dx.doi.org/10.1155/2013/509374
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AT haibowang intenseredupconversionemissionandshapecontrolledsynthesisofgd2o3ybernanocrystals
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